UniSysCat Publications

• Two-Dimensional Covalent Organic Frameworks: Structural Insights across Different Length Scales and Their Impact on Photocatalytic Efficiency, I. E. Khalil, P. Das, A. Thomas, Accounts of Chemical Research 2024, 57, 3138–3150, 10.1021/acs.accounts.4c00491
• Hierarchical Porous Covalent Organic Frameworks: The Influence of Additional Macropores on Photocatalytic Hydrogen Evolution and Hydrogen Peroxide Production, I. E. Khalil, P. Das, H. Küçükkeçeci, V. Dippold, J. Rabeah, W. Tahir, J. Roeser, J. Schmidt, A. Thomas, Chemistry of Materials 2024, 36, 8330–8337, 10.1021/acs.chemmater.4c01298
• An anionic two dimensional covalent organic framework from tetratopic borate centres pillared by lithium ions, D. Asgari, J. Grüneberg, Y. Luo, H. Küçükkeçeci, S. Ghosh, V. Chevelkov, S. Fischer-Lang, J. Roeser, A. Lange, B. Dunn, M. Gradzielski, A. Thomas, Nature Communications 2024, 15, 10.1038/s41467-024-50953-2
• Heteropolyaromatic Covalent Organic Frameworks via One-Pot Multicomponent Reactions, P. Das, G. Chakraborty, N. Friese, J. Roeser, C. Prinz, F. Emmerling, J. Schmidt, A. Thomas, Journal of the American Chemical Society 2024, 146, 17131–17139, 10.1021/jacs.4c02551
• Core–Shell catalyst particles for tandem catalysis: An experimental/numerical approach towards optimal design, N. Bashiri, G. Brösigke, E. Gioria, J. Schmidt, M. Konrad, R. L. Oliveira, M. Geske, F. Rosowski, S. Matera, R. Schomäcker, A. Thomas, J. U. Repke, Chemical Engineering Journal 2024, 495, 153080–0, 10.1016/j.cej.2024.153080
• Covalent Organic Frameworks for Photocatalytic Hydrogen Peroxide Generation, A. Alam, B. Kumbhakar, A. Chakraborty, B. Mishra, S. Ghosh, A. Thomas, P. Pachfule, ACS Materials Letters 2024, 6, 2007–2049, 10.1021/acsmaterialslett.4c00418
• Cobalt(II) Nanoclusters Incorporated in Ordered Mesoporous Al O for Stable and Coke-Resistant Propane Dehydrogenation, F. Ebert, P. Ingale, S. Vogl, S. Praetz, C. Schlesiger, N. Pfister, R. Naumann d’Alnoncourt, B. Roldán Cuenya, A. Thomas, E. Gioria, F. Rosowski, ACS Catalysis 2024, 14, 9993–10008, 10.1021/acscatal.4c02067
• Asymmetric Copper‐Sulphur Sites Promote C–C Coupling for Selective CO Electroreduction to C Products, L. Liang, L. Yang, T. Heine, A. Arinchtein, X. Wang, J. Hübner, J. Schmidt, A. Thomas, P. Strasser, Advanced Energy Materials 2024, 14, 10.1002/aenm.202304224
• Low band gap semiconducting covalent organic framework films with enhanced photocatalytic hydrogen evolution, S. Ghosh, H. Küçükkeçeci, R. P. Paitandi, V. Weigelt, V. Dippold, S. Seki, A. Thomas, Journal of Materials Chemistry A 2024, 12, 247–255, 10.1039/D3TA04552H
• Polyoxometalate (POM) boosting the light-harvesting ability of graphitic carbon nitride for efficient photocatalytic hydrogen production, S. Y. Djoko T., E. Njoyim T., A. D. Nguyen, J. Yang, H. Küçükkeçeci, E. M. Kutorglo, B. Radhakrishnan, K. Schwarzburg, S. Huseyinova, P. Das, M. Tasbihi, M. Schwarze, A. Thomas, R. Schomäcker, Catalysis Science & Technology 2024, 14, 2114–2129, 10.1039/D3CY00496A
• Hydration at Highly Crowded Interfaces, C. Penschke, J. Thomas, C. Bertram, A. Michaelides, K. Morgenstern, P. Saalfrank, U. Bovensiepen, Physical Review Letters 2023, 130, 106202–0, 10.1103/PhysRevLett.130.106202
• Femtosecond Electron-Transfer Dynamics across the D O/Cs /Cu(111) Interface: The Impact of Hydrogen Bonding, J. Thomas, J. Patwari, I. C. Langguth, C. Penschke, P. Zhou, K. Morgenstern, U. Bovensiepen, The Journal of Physical Chemistry C 2023, 127, 23467–23474, 10.1021/acs.jpcc.3c06172
• Dithiophenedione-Based Covalent Organic Frameworks for Supercapacitive Energy Storage, S. Li, B. Kumbhakar, B. Mishra, J. Roeser, N. Chaoui, J. Schmidt, A. Thomas, P. Pachfule, ACS Applied Energy Materials 2023, 6, 9256–9263, 10.1021/acsaem.3c01072
• CuNi Nanoalloys with Tunable Composition and Oxygen Defects for the Enhancement of the Oxygen Evolution Reaction**, E. Gioria, S. Li, A. Mazheika, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, Angewandte Chemie International Edition 2023, 62, 10.1002/anie.202217888
• Solar Light Driven H O Production and Selective Oxidations Using a Covalent Organic Framework Photocatalyst Prepared by a Multicomponent Reaction, P. Das, J. Roeser, A. Thomas, Angewandte Chemie International Edition 2023, 62, 10.1002/anie.202304349
• Covalent organic frameworks, K. T. Tan, S. Ghosh, Z. Wang, F. Wen, D. Rodríguez-San-Miguel, J. Feng, N. Huang, W. Wang, F. Zamora, X. Feng, A. Thomas, D. Jiang, Nature Reviews Methods Primers 2023, 3, 10.1038/s43586-022-00181-z
• Ligating Catalytically Active Peptides onto Microporous Polymers: A General Route Toward Specifically‐Functional High Surface Area Platforms, S. A. Busche, M. Traxler, A. Thomas, H. G. Börner, ChemSusChem 2023, 17, 10.1002/cssc.202301045
• The Catalytic Function of Phosphorus Enriched on the Surface of Vanadium‐based Catalysts in Selective Oxidations, F. Rüther, R. Baumgarten, E. Gioria, K. Knemeyer, J. Xie, R. Kraehnert, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, ChemCatChem 2023, 15, 10.1002/cctc.202300839
• A Triphenylphosphine‐Based Microporous Polymer for a Wittig Reaction Cycle in the Solid State, V. Weigelt, S. Vogl, J. Schmidt, A. Thomas, Angewandte Chemie 2023, 135, 10.1002/ange.202307818
• A Thiazole‐linked Covalent Organic Framework for Lithium‐Sulphur Batteries, R. Yan, B. Mishra, M. Traxler, J. Roeser, N. Chaoui, B. Kumbhakar, J. Schmidt, S. Li, A. Thomas, P. Pachfule, Angewandte Chemie International Edition 2023, 62, 10.1002/anie.202302276
• Solar Light Driven H O Production and Selective Oxidations Using a Covalent Organic Framework Photocatalyst Prepared by a Multicomponent Reaction, P. Das, J. Roeser, A. Thomas, Angewandte Chemie 2023, 135, 10.1002/ange.202304349
• CuNi Nanoalloys with Tunable Composition and Oxygen Defects for the Enhancement of the Oxygen Evolution Reaction**, E. Gioria, S. Li, A. Mazheika, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, Angewandte Chemie 2023, 135, 10.1002/ange.202217888
• Linker Exchange as Facile Method for Post‐Synthetic Modification of β‐Ketoenamine‐linked Covalent Organic Frameworks, V. Dippold, S. Vogl, J. Grüneberg, A. Thomas, Macromolecular Rapid Communications 2023, 44, 10.1002/marc.202300046
• Emerging Materials for Interfacial Solar‐Driven Water Purification, S. Cao, A. Thomas, C. Li, Angewandte Chemie International Edition 2023, 62, 10.1002/anie.202214391
• Core-Sheath Pt-CeO2/Mesoporous SiO2 Electrospun Nanofibers as Catalysts for the Reverse Water Gas Shift Reaction, A. Nejadsalim, N. Bashiri, H. R. Godini, R. L. Oliveira, A. Tufail Shah, M. F. Bekheet, A. Thomas, R. Schomäcker, A. Gurlo, O. Görke, Nanomaterials 2023, 13, 485–0, 10.3390/nano13030485
• Integrating Bifunctionality and Chemical Stability in Covalent Organic Frameworks via One-Pot Multicomponent Reactions for Solar-Driven H O Production, P. Das, G. Chakraborty, J. Roeser, S. Vogl, J. Rabeah, A. Thomas, Journal of the American Chemical Society 2023, 145, 2975–2984, 10.1021/jacs.2c11454
• Boosting the performance of Ni/Al O for the reverse water gas shift reaction through formation of CuNi nanoalloys, E. Gioria, P. Ingale, F. Pohl, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, Catalysis Science & Technology 2022, 12, 474–487, 10.1039/D1CY01585K
• Insights into the light-driven hydrogen evolution reaction of mesoporous graphitic carbon nitride decorated with Pt or Ru nanoparticles, I. Álvarez-Prada, A. D. Nguyen, N. Romero, H. Hou, E. Benazzi, L. Escriche, A. Acharjya, A. Thomas, M. Schwarze, R. Schomäcker, X. Sala, M. Natali, J. García-Antón, M. Tasbihi, Dalton Transactions 2022, 51, 731–740, 10.1039/d1dt03006j
• A Covalent Organic Framework/Graphene Dual-Region Hydrogel for Enhanced Solar-Driven Water Generation, C. Li, S. Cao, J. Lutzki, J. Yang, T. Konegger, F. Kleitz, A. Thomas, Journal of the American Chemical Society 2022, 144, 3083–3090, 10.1021/jacs.1c11689
• Macroscale Conjugated Microporous Polymers: Controlling Versatile Functionalities Over Several Dimensions, W. Zhang, H. Zuo, Z. Cheng, Y. Shi, Z. Guo, N. Meng, A. Thomas, Y. Liao, Advanced Materials 2022, 34, 2104952–0, 10.1002/adma.202104952
• Acridine‐Functionalized Covalent Organic Frameworks (COFs) as Photocatalysts for Metallaphotocatalytic C−N Cross‐Coupling, M. Traxler, S. Gisbertz, P. Pachfule, J. Schmidt, J. Roeser, S. Reischauer, J. Rabeah, B. Pieber, A. Thomas, Angewandte Chemie International Edition 2022, 61, 10.1002/anie.202117738
• Anchoring an Iridium Pincer Complex in a Hydrophobic Microporous Polymer for Application in Continuous‐Flow Alkane Dehydrogenation, M. König, M. Traxler, M. A. Rudolph, J. Schmidt, H. Küçükkeçeci, R. Schomäcker, A. Thomas, ChemCatChem 2022, 14, 10.1002/cctc.202200811
• Intraligand Charge Transfer Enables Visible‐Light‐Mediated Nickel‐Catalyzed Cross‐Coupling Reactions**, C. Cavedon, S. Gisbertz, S. Reischauer, S. Vogl, E. Sperlich, J. H. Burke, R. F. Wallick, S. Schrottke, W. Hsu, L. Anghileri, Y. Pfeifer, N. Richter, C. Teutloff, H. Müller‐Werkmeister, D. Cambié, P. H. Seeberger, J. Vura‐Weis, R. M. van der Veen, A. Thomas, B. Pieber, Angewandte Chemie International Edition 2022, 61, 1–10, 10.1002/anie.202211433
• Covalent Organic Framework (COF) Derived Ni‐N‐C Catalysts for Electrochemical CO Reduction: Unraveling Fundamental Kinetic and Structural Parameters of the Active Sites, C. Li, W. Ju, S. Vijay, J. Timoshenko, K. Mou, D. A. Cullen, J. Yang, X. Wang, P. Pachfule, S. Brückner, H. S. Jeon, F. T. Haase, S. Tsang, C. Rettenmaier, K. Chan, B. Roldan Cuenya, A. Thomas, P. Strasser, Angewandte Chemie International Edition 2022, 61, 202114707–0, 10.1002/anie.202114707
• Screening of Heterogeneous Photocatalysts for Water Splitting, M. Schwarze, T. A. Thiel, A. G. Rana, J. Yang, A. Acharjya, A. D. Nguyen, S. Tameu Djoko, E. M. Kutorglo, M. Tasbihi, M. Minceva, S. Huseyinova, P. Menezes, C. Walter, M. Driess, R. Schomäcker, A. Thomas, Chemie Ingenieur Technik 2022, 94, 1739–1746, 10.1002/cite.202200070
• Programmable Photocatalytic Activity of Multicomponent Covalent Organic Frameworks Used as Metallaphotocatalysts, M. Traxler, S. Reischauer, S. Vogl, J. Roeser, J. Rabeah, C. Penschke, P. Saalfrank, B. Pieber, A. Thomas, Chemistry – A European Journal 2022, 29, 10.1002/chem.202202967
• Constitutional isomerism of the linkages in donor–acceptor covalent organic frameworks and its impact on photocatalysis, J. Yang, S. Ghosh, J. Roeser, A. Acharjya, C. Penschke, Y. Tsutsui, J. Rabeah, T. Wang, S. Y. Djoko Tameu, M. Y. Ye, J. Grüneberg, S. Li, C. Li, R. Schomäcker, R. Van De Krol, S. Seki, P. Saalfrank, A. Thomas, Nature Communications 2022, 13, 6317–0, 10.1038/s41467-022-33875-9
• Design of an active and stable catalyst for dry reforming of methane via molecular layer deposition, P. Ingale, C. Guan, R. Kraehnert, R. Naumann d’Alnoncourt, A. Thomas, F. Rosowski, Catalysis Today 2021, 362, 47–54, 10.1016/j.cattod.2020.04.050
• Covalent organic frameworks (COFs) for electrochemical applications, X. Zhao, P. Pachfule, A. Thomas, Chemical Society Reviews 2021, 50, 6871–6913, 10.1039/D0CS01569E
• Oxygen-evolving catalytic atoms on metal carbides, S. Li, B. Chen, Y. Wang, M. Y. Ye, P. A. van Aken, C. Cheng, A. Thomas, nature materials 2021, 20, 1240–1247, 10.1038/s41563-021-01006-2
• Superstructures of Organic–Polyoxometalate Co‐crystals as Precursors for Hydrogen Evolution Electrocatalysts, S. Li, Z. Zhao, T. Ma, P. Pachfule, A. Thomas, Angewandte Chemie 2021, 134, 10.1002/ange.202112298
• Surface site density and utilization of platinum group metal (PGM)-free Fe–NC and FeNi–NC electrocatalysts for the oxygen reduction reaction, F. Luo, S. Wagner, I. Onishi, S. Selve, S. Li, W. Ju, H. Wang, J. Steinberg, A. Thomas, U. I. Kramm, P. Strasser, Chemical Science 2021, 12, 384–396, 10.1039/D0SC03280H
• Design of PtZn nanoalloy catalysts for propane dehydrogenation through interface tailoring atomic layer deposition, P. Ingale, K. Knemeyer, P. Preikschas, M. Ye, M. Geske, R. Naumann d'Alnoncourt, A. Thomas, F. Rosowski, Catalysis Science & Technology 2021, 11, 484–493, 10.1039/D0CY01528H
• Rational design of tandem catalysts using a core–shell structure approach, E. Gioria, L. Duarte-Correa, N. Bashiri, W. Hetaba, R. Schomaecker, A. Thomas, Nanoscale Advances 2021, 3, 3454–3459, 10.1039/D1NA00310K
• Ruthenium nanoparticles supported on carbon-based nanoallotropes as co-catalyst to enhance the photocatalytic hydrogen evolution activity of carbon nitride, I. Álvarez-Prada, D. Peral, M. Song, J. Muñoz, N. Romero, L. Escriche, A. Acharjya, A. Thomas, R. Schomäcker, M. Schwarze, X. Sala, M. Tasbihi, J. García-Antón, Renewable Energy 2021, 168, 668–675, 10.1016/j.renene.2020.12.070
• Protonated Imine‐Linked Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution, J. Yang, A. Acharjya, M. Ye, J. Rabeah, S. Li, Z. Kochovski, S. Youk, J. Roeser, J. Grüneberg, C. Penschke, M. Schwarze, T. Wang, Y. Lu, R. Krol, M. Oschatz, R. Schomäcker, P. Saalfrank, A. Thomas, Angewandte Chemie International Edition 2021, 60, 19797–19803, 10.1002/anie.202104870
• Pd nanoparticles confined in mesoporous N-doped carbon silica supports: a synergistic effect between catalyst and support, R. L. Oliveira, J. Kerstien, R. Schomäcker, A. Thomas, Catalysis Science & Technology 2020, 10, 1385–1394, 10.1039/c9cy01920k
• Ultralight covalent organic framework/graphene aerogels with hierarchical porosity, C. Li, J. Yang, P. Pachfule, S. Li, M. Y. Ye, J. Schmidt, A. Thomas, Nature Communications 2020, 11, 10.1038/s41467-020-18427-3
• Cobalt‐Exchanged Poly(Heptazine Imides) as Transition Metal–N Electrocatalysts for the Oxygen Evolution Reaction, M. Ye, S. Li, X. Zhao, N. V. Tarakina, C. Teutloff, W. Y. Chow, R. Bittl, A. Thomas, Advanced Materials 2020, 32, 1903942–0, 10.1002/adma.201903942
• Atomic Layer Deposition of ZnO on Mesoporous Silica: Insights into Growth Behavior of ZnO via In-Situ Thermogravimetric Analysis, P. Ingale, K. Knemeyer, M. Piernavieja Hermida, R. Naumann d’Alnoncourt, A. Thomas, F. Rosowski, Nanomaterials 2020, 10, 981–0, 10.3390/nano10050981
• Synthesis of Vinylene-Linked Covalent Organic Frameworks from Acetonitrile: Combining Cyclotrimerization and Aldol Condensation in One Pot, A. Acharjya, L. Longworth-Dunbar, J. Roeser, P. Pachfule, A. Thomas, Journal of the American Chemical Society 2020, 142, 14033–14038, 10.1021/jacs.0c04570
• Promoting Photocatalytic Hydrogen Evolution Activity of Graphitic Carbon Nitride with Hole‐Transfer Agents, A. Indra, R. Beltrán‐Suito, M. Müller, R. P. Sivasankaran, M. Schwarze, A. Acharjya, B. Pradhan, J. Hofkens, A. Brückner, A. Thomas, P. W. Menezes, M. Driess, ChemSusChem 2020, 14, 306–312, 10.1002/cssc.202002500
• Strongly Reducing (Diarylamino)benzene-Based Covalent Organic Framework for Metal-Free Visible Light Photocatalytic H O Generation, C. Krishnaraj, H. Sekhar Jena, L. Bourda, A. Laemont, P. Pachfule, J. Roeser, C. V. Chandran, S. Borgmans, S. M. J. Rogge, K. Leus, C. V. Stevens, J. A. Martens, V. Van Speybroeck, E. Breynaert, A. Thomas, P. Van Der Voort, Journal of the American Chemical Society 2020, 142, 20107–20116, 10.1021/jacs.0c09684
• Immobilization of an Iridium Pincer Complex in a Microporous Polymer for Application in Room‐Temperature Gas Phase Catalysis, M. König, M. Rigo, N. Chaoui, T. Tran Ngoc, J. D. Epping, J. Schmidt, P. Pachfule, M. Ye, M. Trunk, J. F. Teichert, M. Drieß, A. Thomas, Angewandte Chemie International Edition 2020, 59, 19830–19834, 10.1002/anie.202004092
• Confinement of Cobalt Species in Mesoporous N-Doped Carbons and the Impact on Nitroarene Hydrogenation, R. L. Oliveira, M. C. Ben Ghorbel, S. Praetz, D. Meiling, C. Schlesiger, R. Schomäcker, A. Thomas, ACS Sustainable Chemistry & Engineering 2020, 8, 11171–11182, 10.1021/acssuschemeng.0c02365
• Donor–acceptor covalent organic frameworks for visible light induced free radical polymerization, P. Pachfule, A. Acharjya, J. Roeser, R. P. Sivasankaran, M. Y. Ye, A. Brückner, J. Schmidt, A. Thomas, Chemical Science 2019, 10, 8316–8322, 10.1039/c9sc02601k
• Vinylene‐Linked Covalent Organic Frameworks by Base‐Catalyzed Aldol Condensation, A. Acharjya, P. Pachfule, J. Roeser, F. Schmitt, A. Thomas, Angewandte Chemie International Edition 2019, 58, 14865–14870, 10.1002/anie.201905886
• Silica-Templated Covalent Organic Framework-Derived Fe–N-Doped Mesoporous Carbon as Oxygen Reduction Electrocatalyst, X. Zhao, P. Pachfule, S. Li, T. Langenhahn, M. Ye, G. Tian, J. Schmidt, A. Thomas, Chemistry of Materials 2019, 31, 3274–3280, 10.1021/acs.chemmater.9b00204
• Macro/Microporous Covalent Organic Frameworks for Efficient Electrocatalysis, X. Zhao, P. Pachfule, S. Li, T. Langenhahn, M. Ye, C. Schlesiger, S. Praetz, J. Schmidt, A. Thomas, Journal of the American Chemical Society 2019, 141, 6623–6630, 10.1021/jacs.9b01226