Publications in UniSysCat

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Expanding the scope of resonance Raman spectroscopy in hydrogenase research: New observable states and reporter vibrations, C. C. M. Bernitzky, G. Caserta, S. Frielingsdorf, J. Schoknecht, A. Schmidt, P. Scheerer, O. Lenz, P. Hildebrandt, C. Lorent, I. Zebger, M. Horch, Journal of Inorganic Biochemistry 2025, 262, 112741–0, 10.1016/j.jinorgbio.2024.112741
Electron microscopy of liquid–solid interfaces, E. Ortega, S. W. Chee in Encyclopedia of Solid-Liquid Interfaces (Hrsg.: Klaus Wandelt and Gianlorenzo Bussetti), Elsevier, 2024, 0–0, ISBN: 978-0-12-409547-2
Operando Insights into correlating CO coverage and Cu–Au alloying with the selectivity of Au NP-decorated Cu₂O nanocubes during the electrocatalytic CO₂ reduction, C. Rettenmaier, A. Herzog, D. Casari, M. Rüscher, H. S. Jeon, D. Kordus, M. Lopez Luna, S. Kühl, U. Hejral, E. M. Davis, S. W. Chee, J. Timoshenko, D. T. L. Alexander, A. Bergmann, B. Roldan Cuenya, EES Catalysis 2024, 2, 311–323, 10.1039/d3ey00162h
Reversible Structural Evolution of Metal‐Nitrogen‐Doped Carbon Catalysts During CO₂ Electroreduction: An Operando X‐ray Absorption Spectroscopy Study, D. Hursán, J. Timoshenko, E. Ortega, H. S. Jeon, M. Rüscher, A. Herzog, C. Rettenmaier, S. W. Chee, A. Martini, D. Koshy, B. Roldán Cuenya, Advanced Materials 2024, 36, 2307809–0, 10.1002/adma.202307809
Spectromicroscopic study of the transformation with low energy ions of a hematite thin film into a magnetite/hematite epitaxial bilayer, M. J. Prieto, L. de Souza Caldas, L. C. Tănase, T. Schmidt, O. Rodríguez de la Fuente, Ultramicroscopy 2024, 255, 113855–0, 10.1016/j.ultramic.2023.113855
Redox potentials elucidate the electron transfer pathway of NAD+-dependent formate dehydrogenases, B. R. Duffus, M. Gauglitz, C. Teutloff, S. Leimkühler, Journal of Inorganic Biochemistry 2024, 253, 112487–0, 10.1016/j.jinorgbio.2024.112487
Electrochemically assisted SERS sensing of adenosine triphosphate using a carbon microelectrode with composite plasmonic nanostructures, H. Zhou, J. Kneipp, Vibrational Spectroscopy 2024, 131, 103661–0, 10.1016/j.vibspec.2024.103661
Vibrational Dynamics and Spectroscopy of Water at Porous g-C3N4 and C2N Materials, D. Ojha, C. Penschke, P. Saalfrank, Physical Chemistry Chemical Physics 2024, 10.1039/D3CP05964B
Exploiting the full potential of cryo-EM maps, T. Bick, P. M. Dominiak, P. Wendler, BBA Advances 2024, 5, 100113–0, 10.1016/j.bbadva.2024.100113
Towards understanding the crystallization of photosystem II: influence of poly(ethylene glycol) of various molecular sizes on the micelle formation of alkyl maltosides, F. Müh, A. Bothe, A. Zouni, Photosynthesis Research 2024, 10.1007/s11120-024-01079-5
Controlling the Activation at Ni −CO Moieties through Lewis Acid Interactions in the Second Coordination Sphere, S. Wolff, V. Pelmenschikov, R. Müller, M. Ertegi, B. Cula, M. Kaupp, C. Limberg, Chemistry – A European Journal 2024, 10.1002/chem.202303112
In situ/operando plug-flow fixed-bed cell for synchrotron PXRD and XAFS investigations at high temperature, pressure, controlled gas atmosphere and ultra-fast heating, B. Bischoff, M. F. Bekheet, E. Dal Molin, S. Praetz, B. Kanngießer, R. Schomäcker, M. Etter, H. S. Jeppesen, A. Tayal, A. Gurlo, A. Gili, Journal of Synchrotron Radiation 2024, 31, 77–84, 10.1107/S1600577523009591
A quantitative microscopic view on the gas‐phase‐dependent phase transformation from tetragonal to monoclinic ZrO, M. F. Bekheet, L. Schlicker, R. Popescu, W. Riedel, M. Grünbacher, S. Penner, A. Gurlo, Journal of the American Ceramic Society 2024, 10.1111/jace.19749
Enhanced Methanol Synthesis from CO₂ Hydrogenation Achieved by Tuning the Cu–ZnO Interaction in ZnO/Cu O Nanocube Catalysts Supported on ZrO₂ and SiO₂, D. Kordus, S. Widrinna, J. Timoshenko, M. Lopez Luna, C. Rettenmaier, S. W. Chee, E. Ortega, O. Karslioglu, S. Kühl, B. Roldan Cuenya, Journal of the American Chemical Society 2024, 146, 8677–8687, 10.1021/jacs.4c01077
Electrocatalytic Nitrate and Nitrite Reduction toward Ammonia Using Cu₂O Nanocubes: Active Species and Reaction Mechanisms, L. Bai, F. Franco, J. Timoshenko, C. Rettenmaier, F. Scholten, H. S. Jeon, A. Yoon, M. Rüscher, A. Herzog, F. T. Haase, S. Kühl, S. W. Chee, A. Bergmann, R. C. Beatriz, Journal of the American Chemical Society 2024, 146, 9665–9678, 10.1021/jacs.3c13288
ISG15 blocks cardiac glycolysis and ensures sufficient mitochondrial energy production during Coxsackievirus B3 infection, C. Bredow, F. Thery, E. K. Wirth, S. Ochs, M. Kespohl, G. Kleinau, N. Kelm, N. Gimber, J. Schmoranzer, M. Voss, K. Klingel, J. Spranger, K. Renko, M. Ralser, M. Mülleder, A. Heuser, K. P. Knobeloch, P. Scheerer, J. Kirwan, U. Brüning, N. Berndt, F. Impens, A. Beling, Cardiovascular Research 2024, 1–14, 10.1093/cvr/cvae026
Mechanisms of thyrotropin receptor–mediated phenotype variability deciphered by gene mutations and M453T-knockin model, K. Makkonen, M. Jännäri, L. Crisóstomo, M. Kuusi, K. Patyra, V. Melnyk, V. Linnossuo, J. Ojala, R. Ravi, C. Löf, J. A. Mäkelä, P. Miettinen, S. Laakso, M. Ojaniemi, J. Jääskeläinen, M. Laakso, F. Bossowski, B. Sawicka, K. Stożek, A. Bossowski, G. Kleinau, P. Scheerer, FinnGen, M. P. Reeve, J. Kero, JCI Insight 2024, 9, 22–0, 10.1172/jci.insight.167092
A dive into the unknome, J. Rappsilber, Trends in Genetics 2024, 40, 15–16, 10.1016/j.tig.2023.10.011
Structure of the native γ-tubulin ring complex capping spindle microtubules, T. Dendooven, S. Yatskevich, A. Burt, Z. A. Chen, D. Bellini, J. Rappsilber, J. V. Kilmartin, D. Barford, Nature structural & molecular biology 2024, 10.1038/s41594-024-01281-y
Characterization of the Bottlenecks and Pathways for Inhibitor Dissociation from [NiFe] Hydrogenase, F. Sohraby, A. Nunes-Alves, Journal of Chemical Information and Modeling 2024, 10.1021/acs.jcim.4c00187
Coupling CO2 Reduction and Acetyl‐CoA Formation: The Role of a CO Capturing Tunnel in Enzymatic Catalysis, J. Ruickoldt, J. H. Jeoung, M. A. Rudolph, F. Lennartz, J. Kreibich, R. Schomäcker, H. Dobbek, Angewandte Chemie International Edition 2024, 10.1002/anie.202405120
Correlative In Situ Spectro-Microscopy of Supported Single CuO Nanoparticles: Unveiling the Relationships between Morphology and Chemical State during Thermal Reduction, L. de Souza Caldas, M. J. Prieto, L. C. Tănase, A. Tiwari, T. Schmidt, B. Roldan Cuenya, ACS Nano 2024, 18, 13714–13725, 10.1021/acsnano.4c01460
Mechanistic insights into G-protein coupling with an agonist-bound G-protein-coupled receptor, H. Batebi, G. Pérez-Hernández, S. N. Rahman, B. Lan, A. Kamprad, M. Shi, D. Speck, J. K. S. Tiemann, R. Guixà-González, F. Reinhardt, P. F. Stadler, M. M. Papasergi-Scott, G. Skiniotis, P. Scheerer, B. K. Kobilka, J. M. Mathiesen, X. Liu, P. W. Hildebrand, Nature structural & molecular biology 2024, 10.1038/s41594-024-01334-2
Cryo–electron microscopy reveals hydrogen positions and water networks in photosystem II, R. Hussein, A. Graça, J. Forsman, A. O. Aydin, M. Hall, J. Gaetcke, P. Chernev, P. Wendler, H. Dobbek, J. Messinger, A. Zouni, W. P. Schröder, Science 2024, 384, 1349–1355, 10.1126/science.adn6541
Are Melanocortin Receptors Present in Extant Protochordates?, R. L. Ji, S. S. Jiang, G. Kleinau, P. Scheerer, Y. X. Tao, Biomolecules 2024, 14, 1120–0, 10.3390/biom14091120
Simultaneous spectral illumination of microplates for high-throughput optogenetics and photobiology, A. Vogt, R. Paulat, D. Parthier, V. Just, M. Szczepek, P. Scheerer, Q. Xu, A. Möglich, D. Schmitz, B. R. Rost, N. Wenger, Biological Chemistry 2024, 10.1515/hsz-2023-0205
Exploring dynamic solvation kinetics at electrocatalyst surfaces, F. Sarabia, C. Gomez Rodellar, B. Roldan Cuenya, S. Z. Oener, Nature Communications 2024, 15, 8204–0, 10.1038/s41467-024-52499-9
Time-resolved insights into the tunable selectivity of Cu–Zn nanocubes during pulsed CO₂ electroreduction, A. Herzog, M. Rüscher, H. S. Jeon, J. Timoshenko, C. Rettenmaier, U. Hejral, E. M. Davis, F. T. Haase, D. Kordus, S. Kühl, W. Frandsen, A. Bergmann, B. Roldan Cuenya, Energy & Environmental Science 2024, 17, 7081–7096, 10.1039/d4ee02308k
Ultrathin Film Antimony-Doped Tin Oxide Prevents [NiFe] Hydrogenase Inactivation at High Electrode Potentials, V. Davis, S. Frielingsdorf, Q. Hu, P. Elsäßer, B. N. Balzer, O. Lenz, I. Zebger, A. Fischer, ACS Applied Materials & Interfaces 2024, 16, 44802–44816, 10.1021/acsami.4c08218
Nitridated Nickel Mesh as Industrial Water and Alcohol Oxidation Catalyst: Reconstruction and Iron‐Incorporation Matters, S. Ghosh, J. N. Hausmann, L. Reith, G. Vijaykumar, J. Schmidt, K. Laun, S. Berendts, I. Zebger, M. Driess, P. W. Menezes, Advanced Energy Materials 2024, 14, 2400356–0, 10.1002/aenm.202400356
Coupling of the Catalytic Reactions of Formate Dehydrogenase and Hydrogenase in Solution: Insights from in situ IR Spectroscopy and Computations, A. F. T. Waffo, M. Wu‐Lu, S. Katz, S. Frielingsdorf, B. R. Duffus, J. Liedtke, S. Leimkühler, O. Lenz, K. Laun, M. A. Mroginski, I. Zebger, ChemCatChem 2024, 10.1002/cctc.202400794
A soft molecular single-source precursor approach to synthesize a nanostructured Co S (pre)catalyst for efficient water oxidation and biomass valorization, B. Dasgupta, S. Ghosh, C. Walter, M. S. Budde, G. J. Marquardt, H. H. Chen, M. G. M. Breithaupt, T. Yilmaz, C. Garmatter, T. Ahamad, I. Zebger, M. Driess, P. W. Menezes, Journal of Materials Chemistry A 2024, 10.1039/D4TA05436A
The (In)Stability of Heterostructures During the Oxygen Evolution Reaction, I. Mondal, J. N. Hausmann, S. Mebs, S. Kalra, G. Vijaykumar, K. Laun, I. Zebger, S. Selve, H. Dau, M. Driess, P. W. Menezes, Advanced Energy Materials 2024, 14, 10.1002/aenm.202400809
A Strep‐Tag Imprinted Polymer Platform for Heterogenous Bio(electro)catalysis, A. Yarman, A. F. T. Waffo, S. Katz, C. Bernitzky, N. Kovács, P. Borrero, S. Frielingsdorf, E. Supala, J. Dragelj, S. Kurbanoglu, B. Neumann, O. Lenz, M. A. Mroginski, R. E. Gyurcsányi, U. Wollenberger, F. W. Scheller, G. Caserta, I. Zebger, Angewandte Chemie International Edition 2024, 10.1002/anie.202408979
Light‐Induced Electron Transfer in a [NiFe] Hydrogenase Opens a Photochemical Shortcut for Catalytic Dihydrogen Cleavage, C. Karafoulidi‐Retsou, C. Lorent, S. Katz, Y. Rippers, H. Matsuura, Y. Higuchi, I. Zebger, M. Horch, Angewandte Chemie International Edition 2024, 10.1002/anie.202409065
Photoswitchable Endocytosis of Biomolecular Condensates in Giant Vesicles, A. Mangiarotti, M. Aleksanyan, M. Siri, T. Sun, R. Lipowsky, R. Dimova, Advanced Science 2024, 11, 2309864–2309864, 10.1002/advs.202309864
Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides, H. Gao, S. Kwon, H. Kwon, E. Irran, H. F. T. Klare, M. Baik, M. Oestreich, Angewandte Chemie International Edition 2024, 39, 202409582–0, 10.1002/anie.202409582
Silylium-Ion-Initiated Twofold Halodealkylation of Fully Alkylated Silanes, T. Randt, T. He, H. F. T. Klare, M. Oestreich, Synthesis 2024, 56, 3054–3062, 10.1055/a-2350-1323
Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions, P. W. Long, T. He, H. F. T. Klare, M. Oestreich, Synlett 2024, 35, 941–951, 10.1055/a-2188-1842
Questing for homoleptic mononuclear manganese complexes with monodentate O-donor ligands, A. Pérez-Bitrián, J. Munárriz, K. B. Krause, J. Schlögl, K. F. Hoffmann, J. S. Sturm, A. N. Hadi, C. Teutloff, A. Wiesner, C. Limberg, S. Riedel, Chemical Science 2024, 15, 5564–5572, 10.1039/d4sc00543k
Stabilizing Monoatomic Two-Coordinate Bismuth(I) and Bismuth(II) Using a Redox Noninnocent Bis(germylene) Ligand, J. Xu, S. Pan, S. Yao, C. Lorent, C. Teutloff, Z. Zhang, J. Fan, A. Molino, K. B. Krause, J. Schmidt, R. Bittl, C. Limberg, L. Zhao, G. Frenking, M. Driess, Journal of the American Chemical Society 2024, 146, 6025–6036, 10.1021/jacs.3c13016
Water splitting at imine-linked covalent organic frameworks, F. Gottwald, C. Penschke, P. Saalfrank, Physical Chemistry Chemical Physics 2024, 26, 21821–21831, 10.1039/d4cp02019g
ATP-Triggered Fe(CN) CO Synthon Transfer from the Maturase HypCD to the Active Site of Apo-[NiFe]-Hydrogenase, A. Kwiatkowski, G. Caserta, A. C. Schulz, S. Frielingsdorf, V. Pelmenschikov, K. Weisser, A. Belsom, J. Rappsilber, I. Sergueev, C. Limberg, M. A. Mroginski, I. Zebger, O. Lenz, Journal of the American Chemical Society 2024, 10.1021/jacs.4c09791
Synergistic Cooperation of Dual-Phase Redox Catalysts in Chemical Looping Oxidative Coupling of Methane, L. Brody, B. Mosevitzky Lis, A. Pérez Ortiz, M. Kosari, K. Vogt-Lowell, S. Portillo, R. Schomäcker, I. E. Wachs, F. Li, ACS Catalysis 2024, 14, 13112–13125, 10.1021/acscatal.4c03001
Investigation and Comparison of Catalytic Methods to Produce Green CO2-Containing Monomers for Polycarbonates, D. C. Brüggemann, P. H. Isbrücker, D. Zukova, F. R. O. H. Schröter, Y. H. Le, R. Schomäcker, Catalysts 2024, 14, 362–0, 10.3390/catal14060362
Effect of design parameters in nanocatalyst synthesis on pyrolysis for producing diesel-like fuel from waste lubricating oil, R. Y. Parapat, A. T. Laksono, R. I. Fauzi, Y. Maulani, F. Haryanto, A. Noviyanto, M. Schwarze, R. Schomäcker, Nanoscale 2024, 16, 15568–15584, 10.1039/D4NR01183J
One-pot synthesis of iron-doped ceria catalysts for tandem carbon dioxide hydrogenation, A. Gili, M. F. Bekheet, F. Thimm, B. Bischoff, M. Geske, M. Konrad, S. Praetz, C. Schlesiger, S. Selve, A. Gurlo, F. Rosowski, R. Schomäcker, Catalysis Science & Technology 2024, 14, 4174–4186, 10.1039/D4CY00439F
Techno-Economic Assessment of Sustainable H Production and Hydrogenation of Chemicals in a Coupled Photoelectrochemical Device, X. Zhang, Z. Li, L. R. Sinaga, M. Schwarze, R. Schomäcker, R. van de Krol, F. F. Abdi, ACS Sustainable Chemistry & Engineering 2024, 12, 13783–13797, 10.1021/acssuschemeng.4c03463
Specific features of epitope-MIPs and whole-protein MIPs as illustrated for AFP and RBD of SARS-CoV-2, X. Zhang, A. Yarman, N. Kovács, Z. Bognár, R. E. Gyurcsányi, F. F. Bier, F. W. Scheller, Microchimica Acta 2024, 191, 10.1007/s00604-024-06325-0
Trapping of a phenoxyl radical at a non-haem high-spin iron(II) centre, D. Kass, V. A. Larson, T. Corona, U. Kuhlmann, P. Hildebrandt, T. Lohmiller, E. Bill, N. Lehnert, K. Ray, Nature Chemistry 2024, 16, 658–665, 10.1038/s41557-023-01405-9
A high-spin alkylperoxo–iron( ) complex with -anionic ligands: implications for the superoxide reductase mechanism, T. Devi, K. Dutta, J. Deutscher, S. Mebs, U. Kuhlmann, M. Haumann, B. Cula, H. Dau, P. Hildebrandt, K. Ray, Chemical Science 2024, 15, 528–533, 10.1039/D3SC05603A
Identification, Characterization, and Electronic Structures of Interconvertible Cobalt–Oxygen TAML Intermediates, D. D. Malik, W. Ryu, Y. Kim, G. Singh, J. H. Kim, M. Sankaralingam, Y. M. Lee, M. S. Seo, M. Sundararajan, D. Ocampo, M. Roemelt, K. Park, S. H. Kim, M. H. Baik, J. Shearer, K. Ray, S. Fukuzumi, W. Nam, Journal of the American Chemical Society 2024, 146, 13817–13835, 10.1021/jacs.3c14346
Origin of Unprecedented Formation and Reactivity of Fe ═O Species via Oxygen Activation: Role of Noncovalent Interactions and Magnetic Coupling, A. Sen, N. J. Britto, D. Kass, K. Ray, G. Rajaraman, Inorganic Chemistry 2024, 63, 9809–9822, 10.1021/acs.inorgchem.4c00371
A Bioinspired Nonheme Fe –(O )–Cu Complex with an = 1 Ground State, D. Kass, S. Katz, H. Özgen, S. Mebs, M. Haumann, R. García-Serres, H. Dau, P. Hildebrandt, T. Lohmiller, K. Ray, Journal of the American Chemical Society 2024, 146, 24808–24817, 10.1021/jacs.4c04492
Investigation of m- and p-xylene linked bimetallic Ni-cyclam-complexes as potential electrocatalysts for the CO2 reduction, S. Bimmermann, D. Siegmund, K. Ray, U. P. Apfel, Materials Today Catalysis 2024, 6, 100058–0, 10.1016/j.mtcata.2024.100058
A bis-Phenolate Carbene-Supported bis-μ-Oxo Iron(IV/IV) Complex with a [Fe (μ-O) Fe ] Diamond Core Derived from Dioxygen Activation, L. Gravogl, D. Kass, O. Pyschny, F. W. Heinemann, M. Haumann, S. Katz, P. Hildebrandt, H. Dau, A. Swain, R. García-Serres, K. Ray, D. Munz, K. Meyer, Journal of the American Chemical Society 2024, 146, 28757–28769, 10.1021/jacs.4c07582
Unveiling the Spectroscopic Signatures of Poly(3,4-ethylenedioxythiophene) by Controlling Polaron and Bipolaron Concentrations, R. Rubio-Govea, A. Opis-Basilio, A. Torres, M. Sánchez, K. Ray, K. A. Mazzio, The Journal of Physical Chemistry C 2024, 128, 18612–18621, 10.1021/acs.jpcc.4c05602
Long‐Term Stability of Light‐Induced Ti Defects in TiO Nanotubes for Amplified Photoelectrochemical Water Splitting, E. Wierzbicka, E. Szaniawska‐Białas, T. Schultz, A. O. Basilio, D. Siemiaszko, K. Ray, N. Koch, N. Pinna, M. Polański, ChemSusChem 2024, 17, 10.1002/cssc.202301614
Phytate metabolism is mediated by microbial cross-feeding in the gut microbiota, W. M. De Vos, M. Nguyen Trung, M. Davids, G. Liu, M. Rios-Morales, H. Jessen, D. Fiedler, M. Nieuwdorp, T. P. N. Bui, Nature Microbiology 2024, 9, 1812–1827, 10.1038/s41564-024-01698-7
Nanosecond Transient IR Spectroscopy of Halorhodopsin in Living Cells, S. Oldemeyer, M. La Greca, P. Langner, K. L. Lê Công, R. Schlesinger, J. Heberle, Journal of the American Chemical Society 2024, 146, 19118–19127, 10.1021/jacs.4c03891
An Iminophosphinite Pincer Iridium Complex: Synthesis and Catalytic Tool for Alkane Transfer Dehydrogenations, J. Cardozo, O. He, W. Ma, K. Ray, T. Braun, Zeitschrift für Anorganische und Allgemeine Chemie 2024, 650, 10.1002/zaac.202400028
Activation of SO F at a Rhodium PNP Pincer Complex: Ligand Supported S−F Bond Cleavage to Generate NSO F Derivatives, R. Jaeger, S. G. Rachor, M. Ahrens, T. Braun, Chemistry – A European Journal 2024, 30, 10.1002/chem.202401571
A fluorolytic sol–gel route to access an amorphous Zr fluoride catalyst: a useful tool for C–F bond activation, C. Heinekamp, S. Kneiske, A. Guilherme Buzanich, M. Ahrens, T. Braun, F. Emmerling, Catalysis Science & Technology 2024, 14, 673–680, 10.1039/D3CY01439H
C–H and C–F bond activation of fluorinated propenes at Rh: enabling cross-coupling reactions with outer-sphere C–C coupling, M. Talavera, S. Mollasalehi, T. Braun, Chemical Science 2024, 15, 8472–8477, 10.1039/D4SC00951G
Atomistic mechanism of coupling between cytosolic sensor domain and selectivity filter in TREK K2P channels, B. Türkaydin, M. Schewe, E. B. Riel, F. Schulz, J. Biedermann, T. Baukrowitz, H. Sun, Nature Communications 2024, 15, 10.1038/s41467-024-48823-y
Cation Dependence of Enniatin B/Membrane‐Interactions Assessed Using Surface‐Enhanced Infrared Absorption (SEIRA) Spectroscopy, B. D. Gonzalez, E. Forbrig, G. Yao, P. Kielb, M. A. Mroginski, P. Hildebrandt, J. Kozuch, ChemPlusChem 2024, 89, 10.1002/cplu.202400159
High Fluorescence of Phytochromes Does Not Require Chromophore Protonation, S. Katz, H. T. Phan, F. Rieder, F. Seifert, M. Pietzsch, J. Laufer, F. J. Schmitt, P. Hildebrandt, Molecules 2024, 29, 4948–0, 10.3390/molecules29204948
Revisiting Ordered Antifluorite-Type Li Cr N O: Synthesis, Crystal Structure, Theoretical Perspectives, and Catalytic Activity for Ammonia Decomposition, M. Hojamberdiev, E. M. Heppke, T. Bredow, O. Gómez-Cápiro, K. Yubuta, K. Teshima, T. M. Ahamad, C. Lorent, J. A. Baldauf, H. Ruland, R. Pöttgen, M. Lerch, Chemistry of Materials 2024, 36, 9980–9990, 10.1021/acs.chemmater.4c02423
The energy metabolism of Cupriavidus necator in different trophic conditions, M. Jahn, N. Crang, A. H. Gynnå, D. Kabova, S. Frielingsdorf, O. Lenz, E. Charpentier, E. P. Hudson, Applied and Environmental Microbiology 2024, 90, 10.1128/aem.00748-24
Chemoorganotrophic electrofermentation by Cupriavidus necator using redox mediators, A. Gemünde, E. Rossini, O. Lenz, S. Frielingsdorf, D. Holtmann, Bioelectrochemistry 2024, 158, 108694–0, 10.1016/j.bioelechem.2024.108694
Active site switching on high entropy phosphides as bifunctional oxygen electrocatalysts for rechargeable/robust Zn–air battery, R. He, S. Wang, L. Yang, S. Horta, Y. Ding, C. Di, X. Zhang, Y. Xu, M. Ibanez, Y. Zhou, S. Mebs, H. Dau, J. N. Hausmann, W. Huo, P. Menezes, A. Cabot, Energy & Environmental Science 2024, 17, 7193–7208, 10.1039/d4ee01912a
Intermetallic Cobalt Indium Nanoparticles as Oxygen Evolution Reaction Precatalyst: A Non‐Leaching p‐Block Element, J. N. Hausmann, M. Ashton, S. Mebs, C. Walter, S. Selve, M. Haumann, T. Sontheimer, H. Dau, M. Driess, P. W. Menezes, Small 2024, 20, 2309749–0, 10.1002/smll.202309749
Detecting bound ions in ion channels by solid-state NMR experiments on 15N-labelled ammonium ions, C. Öster, S. Lange, K. Hendriks, A. Lange in Potassium Channels: Methods and Protocols, Methods in Molecular Biology (Hrsg.: Simone Furini), Springer, 2024, 0–0, ISBN: 978-1-0716-3817-0
Lipid-polymer nanoparticles to probe the native-like environment of intramembrane rhomboid protease GlpG and its activity, H. Sawczyc, T. Tatsuta, C. Öster, S. Kosteletos, S. Lange, C. Bohg, T. Langer, A. Lange, Nature Communications 2024, 15, 10.1038/s41467-024-51989-0
Bis‐Silylene‐Supported Aluminium Atoms with Aluminylene and Alane Character, A. Saddington, S. Dong, S. Yao, J. Zhu, M. Driess, Angewandte Chemie International Edition 2024, 10.1002/anie.202410790
Intermetallic Cobalt Indium Nanoparticles as Oxygen Evolution Reaction Precatalyst: A Non‐Leaching p‐Block Element, J. N. Hausmann, M. Ashton, S. Mebs, C. Walter, S. Selve, M. Haumann, T. Sontheimer, H. Dau, M. Driess, P. W. Menezes, Small 2024, 20, 10.1002/smll.202309749
Infrared spectroscopy across scales in length and time at BESSY II, A. Veber, L. Puskar, J. Kneipp, U. Schade, Journal of Synchrotron Radiation 2024, 31, 613–621, 10.1107/S1600577524002753
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Well-Defined, Silica-Supported Homobimetallic Nickel Hydride Hydrogenation Catalyst, F. Czerny, K. Searles, P. Šot, J. F. Teichert, P. W. Menezes, C. Copéret, M. Driess, Inorganic Chemistry 2021, 60, 5483–5487, 10.1021/acs.inorgchem.0c03188
A Bifunctional Copper Catalyst Enables Ester Reduction with H : Expanding the Reactivity Space of Nucleophilic Copper Hydrides, B. M. Zimmermann, T. T. Ngoc, D. I. Tzaras, T. Kaicharla, J. F. Teichert, Journal of the American Chemical Society 2021, 143, 16865–16873, 10.1021/jacs.1c09626
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A combination of solid-state NMR and MD simulations reveals the binding mode of a rhomboid protease inhibitor, C. Bohg, C. Öster, T. Utesch, S. Bischoff, S. Lange, C. Shi, H. Sun, A. Lange, Chemical Science 2021, 12, 12754–12762, 10.1039/D1SC02146J
Probing the Intracellular Bio-Nano Interface in Different Cell Lines with Gold Nanostars, C. Spedalieri, G. P. Szekeres, S. Werner, P. Guttmann, J. Kneipp, Nanomaterials 2021, 11, 1183–0, 10.3390/nano11051183
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Structural insights into Cullin4-RING ubiquitin ligase remodelling by Vpr from simian immunodeficiency viruses, S. Banchenko, F. Krupp, C. Gotthold, J. Bürger, A. Graziadei, F. J. O’Reilly, L. Sinn, O. Ruda, J. Rappsilber, C. M. T. Spahn, T. Mielke, I. A. Taylor, D. Schwefel, PLOS Pathogens 2021, 17, 10.1371/journal.ppat.1009775
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Dissecting the activation of insulin degrading enzyme by inositol pyrophosphates and their bisphosphonate analogs, S. Hostachy, T. Utesch, K. Franke, G. L. Dornan, D. Furkert, B. Türkaydin, V. Haucke, H. Sun, D. Fiedler, Chemical Science 2021, 12, 10696–10702, 10.1039/D1SC02975D
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The mechanism behind enhanced reactivity of unsaturated phosphorus(v) electrophiles towards thiols, Y. Park, A. L. Baumann, H. Moon, S. Byrne, M. A. Kasper, S. Hwang, H. Sun, M. H. Baik, C. P. R. Hackenberger, Chemical Science 2021, 12, 8141–8148, 10.1039/D1SC01730F
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Cover Feature: An Iron Porphyrin Complex with Pendant Pyridine Substituents Facilitates Electrocatalytic CO2 Reduction via Second Coordination Sphere Effects, A. R. Ramuglia, V. Budhija, K. H. Ly, M. Marquardt, M. Schwalbe, I. M. Weidinger, ChemCatChem 2021, 13, 3934–3944, 10.1002/cctc.202101193
Exploring the Full Potential of Photocatalytic Carbon Dioxide Reduction Using a Dinuclear Re2Cl2 Complex Assisted by Various Photosensitizers, R. Giereth, M. Obermeier, L. Forschner, M. Karnahl, M. Schwalbe, S. Tschierlei, ChemPhotoChem 2021, 5, 644–653, 10.1002/cptc.202100034
Structural Determination of an Unusual Cu(I)‐Porphyrin‐π‐Bond in a Hetero‐Pacman Cu‐Zn‐Complex, M. Marquardt, B. Cula, V. Budhija, A. Dallmann, M. Schwalbe, Chemistry – A European Journal 2021, 27, 3991–3996, 10.1002/chem.202004945
Protonated Imine‐Linked Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution, J. Yang, A. Acharjya, M. Ye, J. Rabeah, S. Li, Z. Kochovski, S. Youk, J. Roeser, J. Grüneberg, C. Penschke, M. Schwarze, T. Wang, Y. Lu, R. Krol, M. Oschatz, R. Schomäcker, P. Saalfrank, A. Thomas, Angewandte Chemie International Edition 2021, 60, 19797–19803, 10.1002/anie.202104870
Oxygen-evolving catalytic atoms on metal carbides, S. Li, B. Chen, Y. Wang, M. Y. Ye, P. A. van Aken, C. Cheng, A. Thomas, nature materials 2021, 20, 1240–1247, 10.1038/s41563-021-01006-2
Superstructures of Organic–Polyoxometalate Co‐crystals as Precursors for Hydrogen Evolution Electrocatalysts, S. Li, Z. Zhao, T. Ma, P. Pachfule, A. Thomas, Angewandte Chemie 2021, 134, 10.1002/ange.202112298
Surface site density and utilization of platinum group metal (PGM)-free Fe–NC and FeNi–NC electrocatalysts for the oxygen reduction reaction, F. Luo, S. Wagner, I. Onishi, S. Selve, S. Li, W. Ju, H. Wang, J. Steinberg, A. Thomas, U. I. Kramm, P. Strasser, Chemical Science 2021, 12, 384–396, 10.1039/D0SC03280H
Formation, dynamics, and long-term stability of Mn- and Fe-promoted Rh/SiO catalysts in CO hydrogenation, P. Preikschas, J. Bauer, K. Knemeyer, R. Naumann d'Alnoncourt, R. Kraehnert, F. Rosowski, Catalysis Science & Technology 2021, 11, 5802–5815, 10.1039/d1cy00421b
Unraveling Property‐Performance Relationships by Surface Tailoring of Oxidation Catalysts ALD, K. Knemeyer, J. D. Epping, F. Rüther, C. Schulz, B. Frank, P. Müller, R. N. d'Alnoncourt, M. Driess, F. Rosowski, ChemCatChem 2021, 13, 4201–4209, 10.1002/cctc.202100866
Tuning the Rh–FeO Interface in Ethanol Synthesis through Formation Phase Studies at High Pressures of Synthesis Gas, P. Preikschas, M. Plodinec, J. Bauer, R. Kraehnert, R. Naumann d’Alnoncourt, R. Schlögl, M. Driess, F. Rosowski, ACS Catalysis 2021, 11, 4047–4060, 10.1021/acscatal.0c05365
Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms, S. Yao, Y. Xiong, A. Saddington, M. Driess, Chemical Communications 2021, 57, 10139–10153, 10.1039/D1CC04100B
Self‐Supported Electrocatalysts for Practical Water Electrolysis, H. Yang, M. Driess, P. W. Menezes, Advanced Energy Materials 2021, 11, 2102074–0, 10.1002/aenm.202102074
In Situ Formed “Sn In @In Sn O ” Core@Shell Nanoparticles as Electrocatalysts for CO Reduction to Formate, L. C. Pardo Pérez, D. Teschner, E. Willinger, A. Guiet, M. Driess, P. Strasser, A. Fischer, Advanced Functional Materials 2021, 31, 2103601–0, 10.1002/adfm.202103601
Perspective on intermetallics towards efficient electrocatalytic water-splitting, C. Walter, P. W. Menezes, M. Driess, Chemical Science 2021, 12, 8603–8631, 10.1039/D1SC01901E
Evolving Highly Active Oxidic Iron(III) Phase from Corrosion of Intermetallic Iron Silicide to Master Efficient Electrocatalytic Water Oxidation and Selective Oxygenation of 5‐Hydroxymethylfurfural, J. N. Hausmann, R. Beltrán‐Suito, S. Mebs, V. Hlukhyy, T. F. Fässler, H. Dau, M. Driess, P. W. Menezes, Advanced Materials 2021, 33, 1–9, 10.1002/adma.202008823
Distinctly different reactivity of bis(silylenyl)- phosphanyl-silylenyl-substituted -dicarborane towards O , N O and CO, Y. Xiong, S. Yao, A. Ruzicka, M. Driess, Chemical Communications 2021, 57, 5965–5968, 10.1039/D1CC01939B
Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand, S. Yao, A. Kostenko, Y. Xiong, C. Lorent, A. Ruzicka, M. Driess, Angewandte Chemie International Edition 2021, 60, 14864–14868, 10.1002/anie.202103769
New Types of Ge and Ge Assemblies Stabilized by a Carbanionic Dicarborandiyl-Silylene Ligand, Y. Xiong, D. Chen, S. Yao, J. Zhu, A. Ruzicka, M. Driess, Journal of the American Chemical Society 2021, 143, 6229–6237, 10.1021/jacs.1c01722
The Pitfalls of Using Potentiodynamic Polarization Curves for Tafel Analysis in Electrocatalytic Water Splitting, S. Anantharaj, S. Noda, M. Driess, P. W. Menezes, ACS Energy Letters 2021, 6, 1607–1611, 10.1021/acsenergylett.1c00608
Combination of Highly Efficient Electrocatalytic Water Oxidation with Selective Oxygenation of Organic Substrates using Manganese Borophosphates, P. W. Menezes, C. Walter, B. Chakraborty, J. N. Hausmann, I. Zaharieva, A. Frick, E. Hauff, H. Dau, M. Driess, Advanced Materials 2021, 33, 2004098–0, 10.1002/adma.202004098
Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst, M. P. Lücke, S. Yao, M. Driess, Chemical Science 2021, 12, 2909–2915, 10.1039/D0SC06471H
Strategies and Perspectives to Catch the Missing Pieces in Energy‐Efficient Hydrogen Evolution Reaction in Alkaline Media, S. Anantharaj, S. Noda, V. R. Jothi, S. Yi, M. Driess, P. W. Menezes, Angewandte Chemie International Edition 2021, 60, 18981–19006, 10.1002/anie.202015738
Facile Access to an Active γ‐NiOOH Electrocatalyst for Durable Water Oxidation Derived From an Intermetallic Nickel Germanide Precursor, P. W. Menezes, S. Yao, R. Beltrán‐Suito, J. N. Hausmann, P. V. Menezes, M. Driess, Angewandte Chemie International Edition 2021, 60, 4640–4647, 10.1002/anie.202014331
Assessment of hybrid functionals for singlet and triplet excitations: Why do some local hybrid functionals perform so well for triplet excitation energies?, R. Grotjahn, M. Kaupp, The Journal of Chemical Physics 2021, 155, 124108–0, 10.1063/5.0063751
Reliable TDDFT Protocol Based on a Local Hybrid Functional for the Prediction of Vibronic Phosphorescence Spectra Applied to Tris(2,2′-bipyridine)-Metal Complexes, R. Grotjahn, M. Kaupp, The Journal of Physical Chemistry A 2021, 125, 7099–7110, 10.1021/acs.jpca.1c05101
Crystallographic Orientation Dependence of Surface Segregation and Alloying on PdCu Catalysts for CO₂ Hydrogenation, L. Pielsticker, I. Zegkinoglou, Z. K. Han, J. J. Navarro, S. Kunze, O. Karslıoğlu, S. V. Levchenko, B. Roldan Cuenya, The Journal of Physical Chemistry Letters 2021, 12, 2570–2575, 10.1021/acs.jpclett.1c00179
Operando high-pressure investigation of size-controlled CuZn catalysts for the methanol synthesis reaction, N. J. Divins, D. Kordus, J. Timoshenko, I. Sinev, I. Zegkinoglou, A. Bergmann, S. W. Chee, S. Widrinna, O. Karslıoğlu, H. Mistry, M. Lopez Luna, J. Q. Zhong, A. S. Hoffman, A. Boubnov, J. A. Boscoboinik, M. Heggen, R. E. Dunin-Borkowski, S. R. Bare, B. Roldan Cuenya, Nature Communications 2021, 12, 1435–0, 10.1038/s41467-021-21604-7
Low-Temperature Growth of Graphene on a Semiconductor, H. I. Røst, R. K. Chellappan, F. S. Strand, A. Grubišić-Čabo, B. P. Reed, M. J. Prieto, L. C. Tǎnase, L. de Souza Caldas, T. Wongpinij, C. Euaruksakul, T. Schmidt, A. Tadich, B. C. C. Cowie, Z. Li, S. P. Cooil, J. W. Wells, The Journal of Physical Chemistry C 2021, 125, 4243–4252, 10.1021/acs.jpcc.0c10870
In situ and operando electron microscopy in heterogeneous catalysis—insights into multi-scale chemical dynamics, S. W. Chee, T. Lunkenbein, R. Schlögl, B. Roldan Cuenya, Journal of Physics: Condensed Matter 2021, 33, 153001–0, 10.1088/1361-648X/abddfd
Operando Investigation of Ag‐Decorated Cu₂O Nanocube Catalysts with Enhanced CO₂ Electroreduction toward Liquid Products, A. Herzog, A. Bergmann, H. S. Jeon, J. Timoshenko, S. Kühl, C. Rettenmaier, M. Lopez Luna, F. T. Haase, B. Roldan Cuenya, Angewandte Chemie International Edition 2021, 60, 7426–7435, 10.1002/anie.202017070
Selectivity Control of Cu Nanocrystals in a Gas-Fed Flow Cell through CO₂ Pulsed Electroreduction, H. S. Jeon, J. Timoshenko, C. Rettenmaier, A. Herzog, A. Yoon, S. W. Chee, S. Oener, U. Hejral, F. T. Haase, B. Roldan Cuenya, Journal of the American Chemical Society 2021, 143, 7578–7587, 10.1021/jacs.1c03443
Role of the Oxide Support on the Structural and Chemical Evolution of Fe Catalysts during the Hydrogenation of CO₂, M. Lopez Luna, J. Timoshenko, D. Kordus, C. Rettenmaier, S. W. Chee, A. S. Hoffman, S. R. Bare, S. Shaikhutdinov, B. Roldan Cuenya, ACS Catalysis 2021, 11, 6175–6185, 10.1021/acscatal.1c01549
Revealing the CO Coverage-Driven C–C Coupling Mechanism for Electrochemical CO₂ Reduction on Cu₂O Nanocubes Raman Spectroscopy, C. Zhan, F. Dattila, C. Rettenmaier, A. Bergmann, S. Kühl, R. García-Muelas, N. López, B. Roldan Cuenya, ACS Catalysis 2021, 11, 7694–7701, 10.1021/acscatal.1c01478
A Simplified Method for Patterning Graphene on Dielectric Layers, H. I. Røst, B. P. Reed, F. S. Strand, J. A. Durk, D. A. Evans, A. Grubišić-Čabo, G. Wan, M. Cattelan, M. J. Prieto, D. M. Gottlob, L. C. Tănase, L. de Souza Caldas, T. Schmidt, A. Tadich, B. C. C. Cowie, R. K. Chellappan, J. W. Wells, S. P. Cooil, ACS Applied Materials & Interfaces 2021, 13, 37510–37516, 10.1021/acsami.1c09987
Identifying Structure–Selectivity Correlations in the Electrochemical Reduction of CO₂: A Comparison of Well‐Ordered Atomically Clean and Chemically Etched Copper Single‐Crystal Surfaces, F. Scholten, K. C. Nguyen, J. P. Bruce, M. Heyde, B. Roldan Cuenya, Angewandte Chemie International Edition 2021, 60, 19169–19175, 10.1002/anie.202103102
Plasma-assisted oxidation of Cu(100) and Cu(111), S. Kunze, L. C. Tănase, M. J. Prieto, P. Grosse, F. Scholten, L. de Souza Caldas, D. van Vörden, T. Schmidt, B. Roldan Cuenya, Chemical Science 2021, 12, 14241–14253, 10.1039/D1SC04861A
Dynamic transformation of cubic copper catalysts during CO₂ electroreduction and its impact on catalytic selectivity, P. Grosse, A. Yoon, C. Rettenmaier, A. Herzog, S. W. Chee, B. Roldan Cuenya, Nature Communications 2021, 12, 6736–0, 10.1038/s41467-021-26743-5
Ruthenium nanoparticles supported on carbon-based nanoallotropes as co-catalyst to enhance the photocatalytic hydrogen evolution activity of carbon nitride, I. Álvarez-Prada, D. Peral, M. Song, J. Muñoz, N. Romero, L. Escriche, A. Acharjya, A. Thomas, R. Schomäcker, M. Schwarze, X. Sala, M. Tasbihi, J. García-Antón, Renewable Energy 2021, 168, 668–675, 10.1016/j.renene.2020.12.070
Silicon oxycarbonitride ceramic containing nickel nanoparticles: from design to catalytic application, J. Wang, A. Gili, M. Grünbacher, S. Praetz, J. D. Epping, O. Görke, G. Schuck, S. Penner, C. Schlesiger, R. Schomäcker, A. Gurlo, M. F. Bekheet, Materials Advances 2021, 2, 1715–1730, 10.1039/d0ma00917b
Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO, P. Zimmermann, A. F. R. Kilpatrick, D. Ar, S. Demeshko, B. Cula, C. Limberg, Chemical Communications 2021, 57, 875–878, 10.1039/D0CC06983C
The Properties of Hydrotris(3‐mesitylpyrazol‐1‐yl) Borate Iron(II) Complexes with Aryl Carboxylate Co‐ligands – Stabilization of an Iron(III) Alkylperoxide, L. Müller, K. Baturin, S. Hoof, C. Lau, C. Herwig, C. Limberg, Zeitschrift für Anorganische und Allgemeine Chemie 2021, 647, 385–395, 10.1002/zaac.202000437
Transformation of Formazanate at Nickel(II) Centers to Give a Singly Reduced Nickel Complex with Azoiminate Radical Ligands and Its Reactivity toward Dioxygen, D. Ar, A. F. R. Kilpatrick, B. Cula, C. Herwig, C. Limberg, Inorganic Chemistry 2021, 60, 13844–13853, 10.1021/acs.inorgchem.0c03761
Binding of a TlCl Entity by a Tetragold Tetramercaptothiacalixarene Metalloligand via Metallophilic Interactions, N. Frank, I. Pryjomska‐Ray, L. Grubert, S. Hecht, D. Usvyat, C. Limberg, Chemistry – A European Journal 2021, 27, 8344–8349, 10.1002/chem.202100298
Mimicking of the histidine brace structural motif in molecular copper(I) compounds, R. Peifer, L. Müller, S. Hoof, F. Beckmann, B. Cula, C. Limberg, Zeitschrift für Anorganische und Allgemeine Chemie 2021, 647, 1789–1796, 10.1002/zaac.202100145
Emerging concepts in photocatalytic organic synthesis, S. Reischauer, B. Pieber, iScience 2021, 24, 102209–0, 10.1016/j.isci.2021.102209
Visible-Light-Mediated Oxidative Debenzylation Enables the Use of Benzyl Ethers as Temporary Protecting Groups, C. Cavedon, E. T. Sletten, A. Madani, O. Niemeyer, P. H. Seeberger, B. Pieber, Organic Letters 2021, 23, 514–518, 10.1021/acs.orglett.0c04026
Chromoselective Photocatalysis Enables Stereocomplementary Biocatalytic Pathways**, L. Schmermund, S. Reischauer, S. Bierbaumer, C. K. Winkler, A. Diaz‐Rodriguez, L. J. Edwards, S. Kara, T. Mielke, J. Cartwright, G. Grogan, B. Pieber, W. Kroutil, Angewandte Chemie International Edition 2021, 60, 6965–6969, 10.1002/anie.202100164
Recyclable, Bifunctional Metallaphotocatalysts for C−S Cross‐Coupling Reactions, S. Reischauer, B. Pieber, ChemPhotoChem 2021, 5, 716–720, 10.1002/cptc.202100062
Carbon dot/TiO nanocomposites as photocatalysts for metallaphotocatalytic carbon–heteroatom cross-couplings, Z. Zhao, S. Reischauer, B. Pieber, M. Delbianco, Green Chemistry 2021, 23, 4524–4530, 10.1039/d1gc01284c
Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts, H. F. T. Klare, L. Albers, L. Süsse, S. Keess, T. Müller, M. Oestreich, Chemical Reviews 2021, 121, 5889–5985, 10.1021/acs.chemrev.0c00855
Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes, T. He, G. Wang, P. W. Long, S. Kemper, E. Irran, H. F. T. Klare, M. Oestreich, Chemical Science 2021, 12, 569–575, 10.1039/D0SC05553K
ATP Binding and a Second Reduction Enables a Conformationally Gated Uphill Electron Transfer, F. Neumann, H. Dobbek, ACS Catalysis 2021, 11, 8565–8575, 10.1021/acscatal.1c01038
Bimetallic Mn, Fe, Co, and Ni Sites in a Four-Helix Bundle Protein: Metal Binding, Structure, and Peroxide Activation, J. H. Jeoung, S. Rünger, M. Haumann, B. Neumann, F. Klemke, V. Davis, A. Fischer, H. Dau, U. Wollenberger, H. Dobbek, Inorganic Chemistry 2021, 60, 17498–17508, 10.1021/acs.inorgchem.1c01919
Understanding active sites in molecular (photo)electrocatalysis through complementary vibrational spectroelectrochemistry, K. H. Ly, I. M. Weidinger, Chemical Communications 2021, 57, 2328–2342, 10.1039/d0cc07376h
A Resonance Raman Marker Band Characterizes the Slow and Fast Form of Cytochrome Oxidase, F. Kruse, A. D. Nguyen, J. Dragelj, J. Heberle, P. Hildebrandt, M. A. Mroginski, I. M. Weidinger, Journal of the American Chemical Society 2021, 143, 2769–2776, 10.1021/jacs.0c10767
The Role of Metal–Organic Frameworks in Moderating Platinum-Based Ethanol Electrooxidation Catalysts, J. B. Fritzke, C. Eßbach, P. Wollmann, A. H. Khan, I. Senkovska, I. M. Weidinger, S. Kaskel, E. Brunner, The Journal of Physical Chemistry C 2021, 125, 14263–14274, 10.1021/acs.jpcc.1c02563
Thiophene‐Based Conjugated Acetylenic Polymers with Dual Active Sites for Efficient Co‐Catalyst‐Free Photoelectrochemical Water Reduction in Alkaline Medium, M. Borrelli, C. J. Querebillo, D. L. Pastoetter, T. Wang, A. Milani, C. Casari, H. Khoa Ly, F. He, Y. Hou, C. Neumann, A. Turchanin, H. Sun, I. M. Weidinger, X. Feng, Angewandte Chemie International Edition 2021, 60, 18876–18881, 10.1002/anie.202104469
Thiophen‐basierte konjugierte acetylenische Polymere mit dualen aktiven Zentren für effiziente Cokatalysator‐freie photoelektrochemische Wasserreduktion im alkalischen Medium, M. Borrelli, C. J. Querebillo, D. L. Pastoetter, T. Wang, A. Milani, C. Casari, H. Khoa Ly, F. He, Y. Hou, C. Neumann, A. Turchanin, H. Sun, I. M. Weidinger, X. Feng, Angewandte Chemie 2021, 133, 19025–19031, 10.1002/ange.202104469
An Iron Porphyrin Complex with Pendant Pyridine Substituents Facilitates Electrocatalytic CO Reduction via Second Coordination Sphere Effects, A. R. Ramuglia, V. Budhija, K. H. Ly, M. Marquardt, M. Schwalbe, I. M. Weidinger, ChemCatChem 2021, 13, 3934–3944, 10.1002/cctc.202100625
Boosting the Electrocatalytic Conversion of Nitrogen to Ammonia on Metal-Phthalocyanine-Based Two-Dimensional Conjugated Covalent Organic Frameworks, H. Zhong, M. Wang, M. Ghorbani-Asl, J. Zhang, K. H. Ly, Z. Liao, G. Chen, Y. Wei, B. P. Biswal, E. Zschech, I. M. Weidinger, A. V. Krasheninnikov, R. Dong, X. Feng, Journal of the American Chemical Society 2021, 143, 19992–20000, 10.1021/jacs.1c11158
Molecular Details on Multiple Cofactor Containing Redox Metalloproteins Revealed by Infrared and Resonance Raman Spectroscopies, C. M. Silveira, L. Zuccarello, C. Barbosa, G. Caserta, I. Zebger, P. Hildebrandt, S. Todorovic, Molecules 2021, 26, 4852–0, 10.3390/molecules26164852
Structural plasticity of the selectivity filter in a nonselective ion channel, R. N. Roy, K. Hendriks, W. Kopec, S. Abdolvand, K. L. Weiss, B. L. de Groot, A. Lange, H. Sun, L. Coates, IUCrJ 2021, 8, 421–430, 10.1107/S205225252100213X
Sodium Ions Do Not Stabilize the Selectivity Filter of a Potassium Channel, K. Hendriks, C. Öster, C. Shi, H. Sun, A. Lange, Journal of Molecular Biology 2021, 433, 167091–0, 10.1016/j.jmb.2021.167091
Structural Plasticity of the Selectivity Filter in Cation Channels, K. Hendriks, C. Öster, A. Lange, Frontiers in Physiology 2021, 12, 10.3389/fphys.2021.792958
Spectroscopic Characterization of a Reactive [Cu (μ‐OH) ] Intermediate in Cu/TEMPO Catalyzed Aerobic Alcohol Oxidation Reaction, K. Warm, G. Tripodi, E. Andris, S. Mebs, U. Kuhlmann, H. Dau, P. Hildebrandt, J. Roithová, K. Ray, Angewandte Chemie International Edition 2021, 60, 23018–23024, 10.1002/anie.202108442
A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C−H Bond Oxidation Reactions, K. Warm, A. Paskin, U. Kuhlmann, E. Bill, M. Swart, M. Haumann, H. Dau, P. Hildebrandt, K. Ray, Angewandte Chemie International Edition 2021, 60, 6752–6756, 10.1002/anie.202015896
A bioinspired oxoiron( ) motif supported on a N S macrocyclic ligand, J. Deutscher, P. Gerschel, K. Warm, U. Kuhlmann, S. Mebs, M. Haumann, H. Dau, P. Hildebrandt, U. P. Apfel, K. Ray, Chemical Communications 2021, 57, 2947–2950, 10.1039/d1cc00250c
Electrografted Interfaces on Metal Oxide Electrodes for Enzyme Immobilization and Bioelectrocatalysis, T. G. A. A. Harris, N. Heidary, S. Frielingsdorf, S. Rauwerdink, A. Tahraoui, O. Lenz, I. Zebger, A. Fischer, ChemElectroChem 2021, 8, 1329–1336, 10.1002/celc.202100020
Stable, but still reactive – investigations on the effects of Lewis acid binding on copper nitrene intermediates, K. Warm, I. Monte Pérez, U. Kuhlmann, P. Hildebrandt, E. Farquhar, M. Swart, K. Ray, Zeitschrift für Anorganische und Allgemeine Chemie 2021, 647, 1495–1502, 10.1002/zaac.202100092
Electronic and Structural Properties of the Double Cubane Iron-Sulfur Cluster, N. Elghobashi-Meinhardt, D. Tombolelli, M. A. Mroginski, Catalysts 2021, 11, 245–0, 10.3390/catal11020245
Voltammetry and Single‐Molecule In Situ Scanning Tunnelling Microscopy of the Redox Metalloenzyme Human Sulfite Oxidase, J. Yan, E. E. Frøkjær, C. Engelbrekt, S. Leimkühler, J. Ulstrup, U. Wollenberger, X. Xiao, J. Zhang, ChemElectroChem 2021, 8, 164–171, 10.1002/celc.202001258
Investigation of a potential electrogenic transport-system for -inositol in the small intestine of laying hens, K. Röhm, F. Gonzalez-Uarquin, R. K. Harmel, M. Nguyen Trung, M. Diener, D. Fiedler, K. Huber, J. Seifert, British Poultry Science 2021, 63, 91–97, 10.1080/00071668.2021.1958301
Deoxygenation of Nitrous Oxide and Nitro Compounds Using Bis(N‐Heterocyclic Silylene)Amido Iron Complexes as Catalysts, X. Chen, H. Wang, S. Du, M. Driess, Z. Mo, Angewandte Chemie International Edition 2021, 61, 10.1002/anie.202114598
A Genuine Stannylone with a Monoatomic Two‐Coordinate Tin(0) Atom Supported by a Bis(silylene) Ligand, J. Xu, C. Dai, S. Yao, J. Zhu, M. Driess, Angewandte Chemie International Edition 2021, 61, 10.1002/anie.202114073
A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene), M. Luecke, L. Giarrana, A. Kostenko, T. Gensch, S. Yao, M. Driess, Angewandte Chemie International Edition 2021, 61, 10.1002/anie.202110398
Preparation and functionalization of free-standing nitrogen-doped carbon-based catalyst electrodes for electrocatalytic N2 fixation, Q. Qin, F. Brandi, B. Badamdorj, M. Oschatz, M. Al-Naji, Molecular Catalysis 2021, 515, 111935–0, 10.1016/j.mcat.2021.111935
Shulin packages axonemal outer dynein arms for ciliary targeting, G. R. Mali, F. A. Ali, C. K. Lau, F. Begum, J. Boulanger, J. D. Howe, Z. A. Chen, J. Rappsilber, M. Skehel, A. P. Carter, Science 2021, 371, 910–916, 10.1126/science.abe0526
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Macro/Microporous Covalent Organic Frameworks for Efficient Electrocatalysis, X. Zhao, P. Pachfule, S. Li, T. Langenhahn, M. Ye, C. Schlesiger, S. Praetz, J. Schmidt, A. Thomas, Journal of the American Chemical Society 2019, 141, 6623–6630, 10.1021/jacs.9b01226
Design of a light-gated proton channel based on the crystal structure of rhodopsin, R. Fudim, M. Szczepek, J. Vierock, A. Vogt, A. Schmidt, G. Kleinau, P. Fischer, F. Bartl, P. Scheerer, P. Hegemann, Science Signaling 2019, 12, 10.1126/scisignal.aav4203
Site‐Resolved Observation of Vibrational Energy Transfer Using a Genetically Encoded Ultrafast Heater, T. Baumann, M. Hauf, F. Schildhauer, K. B. Eberl, P. M. Durkin, E. Deniz, J. G. Löffler, C. G. Acevedo‐Rocha, J. Jaric, B. M. Martins, H. Dobbek, J. Bredenbeck, N. Budisa, Angewandte Chemie International Edition 2019, 58, 2899–2903, 10.1002/anie.201812995
X‐ray Crystallography and Vibrational Spectroscopy Reveal the Key Determinants of Biocatalytic Dihydrogen Cycling by [NiFe] Hydrogenases, Y. Ilina, C. Lorent, S. Katz, J. Jeoung, S. Shima, M. Horch, I. Zebger, H. Dobbek, Angewandte Chemie International Edition 2019, 58, 18710–18714, 10.1002/anie.201908258
Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates, J. A. Birrell, V. Pelmenschikov, N. Mishra, H. Wang, Y. Yoda, K. Tamasaku, T. B. Rauchfuss, S. P. Cramer, W. Lubitz, S. DeBeer, Journal of the American Chemical Society 2019, 142, 222–232, 10.1021/jacs.9b09745
Three-Dimensional Bioelectrodes Utilizing Graphene Based Bioink, R. M. L. Werchmeister, J. Tang, X. Xiao, U. Wollenberger, H. A. Hjuler, J. Ulstrup, J. Zhang, Journal of The Electrochemical Society 2019, 166, 10.1149/2.0261916jes
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Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions, Q. Wu, A. Roy, E. Irran, Z. Qu, S. Grimme, H. F. T. Klare, M. Oestreich, Angewandte Chemie International Edition 2019, 58, 17307–17311, 10.1002/anie.201911282
Gradient metal nanoislands as a unified surface enhanced Raman scattering and surface enhanced infrared absorption platform for analytics, D. Gkogkou, T. Shaykhutdinov, C. Kratz, T. W. H. Oates, P. Hildebrandt, I. M. Weidinger, K. H. Ly, N. Esser, K. Hinrichs, The Analyst 2019, 144, 5271–5276, 10.1039/C9an00839J
Influence of Mesityl and Thiophene Peripheral Substituents on Surface Attachment, Redox Chemistry, and ORR Activity of Molecular Iron Porphyrin Catalysts on Electrodes, R. Götz, K. H. Ly, P. Wrzolek, A. Dianat, A. Croy, G. Cuniberti, P. Hildebrandt, M. Schwalbe, I. M. Weidinger, Inorganic Chemistry 2019, 58, 10637–10647, 10.1021/acs.inorgchem.9b00043
Accelerated Photo‐Induced Degradation of Benzidine‐ ‐Aminothiophenolate Immobilized at Light‐Enhancing TiO Nanotube Electrodes, C. J. Querebillo, I. H. Öner, P. Hildebrandt, K. H. Ly, I. M. Weidinger, Chemistry – A European Journal 2019, 25, 16048–16053, 10.1002/chem.201902963
Molecular Engineering of Conjugated Acetylenic Polymers for Efficient Cocatalyst‐free Photoelectrochemical Water Reduction, H. Sun, I. H. Öner, T. Wang, T. Zhang, O. Selyshchev, C. Neumann, Y. Fu, Z. Liao, S. Xu, Y. Hou, A. Turchanin, D. R. T. Zahn, E. Zschech, I. M. Weidinger, J. Zhang, X. Feng, Angewandte Chemie 2019, 131, 10476–10482, 10.1002/ange.201904978
A Phthalocyanine‐Based Layered Two‐Dimensional Conjugated Metal–Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction, H. Zhong, K. H. Ly, M. Wang, Y. Krupskaya, X. Han, J. Zhang, J. Zhang, V. Kataev, B. Büchner, I. M. Weidinger, S. Kaskel, P. Liu, M. Chen, R. Dong, X. Feng, Angewandte Chemie 2019, 131, 10787–10792, 10.1002/ange.201907002
Semiheterogeneous Dual Nickel/Photocatalytic (Thio)etherification Using Carbon Nitrides, C. Cavedon, A. Madani, P. H. Seeberger, B. Pieber, Organic Letters 2019, 21, 5331–5334, 10.1021/acs.orglett.9b01957
Theoretical Surface Science Beyond Gradient-Corrected Density Functional Theory: Water at α-Al₂O₃(0001) as a Case Study, S. Heiden, D. Usvyat, P. Saalfrank, The Journal of Physical Chemistry C 2019, 123, 6675–6684, 10.1021/acs.jpcc.9b00407
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Unlocking the Spatial Control of Secondary Metabolism Uncovers Hidden Natural Product Diversity in, D. Dehm, J. Krumbholz, M. Baunach, V. Wiebach, K. Hinrichs, A. Guljamow, T. Tabuchi, H. Jenke-Kodama, R. D. Süssmuth, E. Dittmann, ACS Chemical Biology 2019, 14, 1271–1279, 10.1021/acschembio.9b00240
Switching from a Chromium(IV) Peroxide to a Chromium(III) Superoxide upon Coordination of a Donor in the trans Position, M. L. Wind, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg, Journal of the American Chemical Society 2019, 141, 14068–14072, 10.1021/jacs.9b06826
The Influence of Alkali Metal Ions on the Stability and Reactivity of Chromium(III) Superoxide Moieties Spanned by Siloxide Ligands, M. Wind, S. Hoof, C. Herwig, B. Braun‐Cula, C. Limberg, Chemistry – A European Journal 2019, 25, 5743–5750, 10.1002/chem.201900236
A Polysiloxide Complex with two Chromium(III) η ‐Superoxo Moieties, M. Wind, B. Braun‐Cula, F. Schax, C. Herwig, C. Limberg, Israel Journal of Chemistry 2019, 10.1002/ijch.201900119
Silica-Templated Covalent Organic Framework-Derived Fe–N-Doped Mesoporous Carbon as Oxygen Reduction Electrocatalyst, X. Zhao, P. Pachfule, S. Li, T. Langenhahn, M. Ye, G. Tian, J. Schmidt, A. Thomas, Chemistry of Materials 2019, 31, 3274–3280, 10.1021/acs.chemmater.9b00204
Vinylene‐Linked Covalent Organic Frameworks by Base‐Catalyzed Aldol Condensation, A. Acharjya, P. Pachfule, J. Roeser, F. Schmitt, A. Thomas, Angewandte Chemie International Edition 2019, 58, 14865–14870, 10.1002/anie.201905886
Donor–acceptor covalent organic frameworks for visible light induced free radical polymerization, P. Pachfule, A. Acharjya, J. Roeser, R. P. Sivasankaran, M. Y. Ye, A. Brückner, J. Schmidt, A. Thomas, Chemical Science 2019, 10, 8316–8322, 10.1039/c9sc02601k
Operando Insights into Nanoparticle Transformations during Catalysis, A. Bergmann, B. Roldan Cuenya, ACS Catalysis 2019, 9, 10020–10043, 10.1021/acscatal.9b01831
Selective CO Electroreduction to Ethylene and Multicarbon Alcohols via Electrolyte‐Driven Nanostructuring, D. Gao, I. Sinev, F. Scholten, R. M. Arán‐Ais, N. J. Divins, K. Kvashnina, J. Timoshenko, B. Roldan Cuenya, Angewandte Chemie International Edition 2019, 58, 17047–17053, 10.1002/anie.201910155
Operando Insight into the Correlation between the Structure and Composition of CuZn Nanoparticles and Their Selectivity for the Electrochemical CO Reduction, H. S. Jeon, J. Timoshenko, F. Scholten, I. Sinev, A. Herzog, F. T. Haase, B. Roldan Cuenya, Journal of the American Chemical Society 2019, 141, 19879–19887, 10.1021/jacs.9b10709
Enhanced Electrocatalytic N Reduction via Partial Anion Substitution in Titanium Oxide–Carbon Composites, Q. Qin, Y. Zhao, M. Schmallegger, T. Heil, J. Schmidt, R. Walczak, G. Gescheidt‐Demner, H. Jiao, M. Oschatz, Angewandte Chemie International Edition 2019, 58, 13101–13106, 10.1002/anie.201906056
Electrochemical Fixation of Nitrogen and Its Coupling with Biomass Valorization with a Strongly Adsorbing and Defect Optimized Boron–Carbon–Nitrogen Catalyst, Q. Qin, T. Heil, J. Schmidt, M. Schmallegger, G. Gescheidt, M. Antonietti, M. Oschatz, ACS Applied Energy Materials 2019, 2, 8359–8365, 10.1021/acsaem.9b01852
Electrochemical MIP Sensor for Butyrylcholinesterase, G. Ozcelikay, S. Kurbanoglu, X. Zhang, C. Kosak Soz, U. Wollenberger, S. A. Ozkan, A. Yarman, F. W. Scheller, Polymers 2019, 11, 1970–0, 10.3390/polym11121970
In-Cell Synthesis of Bioorthogonal Alkene Tag S-Allyl-Homocysteine and Its Coupling with Reprogrammed Translation, S. Nojoumi, Y. Ma, S. Schwagerus, C. P. R. Hackenberger, N. Budisa, International Journal of Molecular Sciences 2019, 20, 2299–0, 10.3390/ijms20092299
Computational Aminoacyl-tRNA Synthetase Library Design for Photocaged Tyrosine, T. Baumann, M. Hauf, F. Richter, S. Albers, A. Möglich, Z. Ignatova, N. Budisa, International Journal of Molecular Sciences 2019, 20, 2343–0, 10.3390/ijms20092343
The Alanine World Model for the Development of the Amino Acid Repertoire in Protein Biosynthesis, V. Kubyshkin, N. Budisa, International Journal of Molecular Sciences 2019, 20, 5507–0, 10.3390/ijms20215507
Promotion of the collagen triple helix in a hydrophobic environment, V. Kubyshkin, N. Budisa, Organic & Biomolecular Chemistry 2019, 17, 2502–2507, 10.1039/c9ob00070d
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Anticipating alien cells with alternative genetic codes: away from the alanine world!, V. Kubyshkin, N. Budisa, Current Opinion in Biotechnology 2019, 60, 242–249, 10.1016/j.copbio.2019.05.006
Expanding the DOPA Universe with Genetically Encoded, Mussel‐Inspired Bioadhesives for Material Sciences and Medicine, N. Budisa, T. Schneider, ChemBioChem 2019, 20, 2163–2190, 10.1002/cbic.201900030
Shining a Light on Proteolysis Targeting Chimeras, E. Teichmann, S. Hecht, ACS Central Science 2019, 5, 1645–1647, 10.1021/acscentsci.9b00955
External Reversal of Chirality Transfer in Photoswitches, C. Jurissek, F. Berger, F. Eisenreich, M. Kathan, S. Hecht, Angewandte Chemie International Edition 2019, 58, 1945–1949, 10.1002/anie.201812284
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Structure and Dynamics of the Rhomboid Protease GlpG in Liposomes Studied by Solid-State NMR, C. Shi, C. Öster, C. Bohg, L. Li, S. Lange, V. Chevelkov, A. Lange, Journal of the American Chemical Society 2019, 141, 17314–17321, 10.1021/jacs.9b08952
Mechanistic reaction pathways of enhanced ethylene yields during electroreduction of CO2–CO co-feeds on Cu and Cu-tandem electrocatalysts, X. Wang, J. F. de Araújo, W. Ju, A. Bagger, H. Schmies, S. Kühl, J. Rossmeisl, P. Strasser, Nature Nanotechnology 2019, 14, 1063–1070, 10.1038/s41565-019-0551-6
Unraveling Mechanistic Reaction Pathways of the Electrochemical CO Reduction on Fe–N–C Single-Site Catalysts, W. Ju, A. Bagger, X. Wang, Y. Tsai, F. Luo, T. Möller, H. Wang, J. Rossmeisl, A. S. Varela, P. Strasser, ACS Energy Letters 2019, 4, 1663–1671, 10.1021/acsenergylett.9b01049
Electromodified NiFe Alloys as Electrocatalysts for Water Oxidation: Mechanistic Implications of Time‐Resolved UV/Vis Tracking of Oxidation State Changes, S. Loos, I. Zaharieva, P. Chernev, A. Lißner, H. Dau, ChemSusChem 2019, 12, 1966–1976, 10.1002/cssc.201802737
Carbon fibre paper coated by a layered manganese oxide: a nano-structured electrocatalyst for water-oxidation with high activity over a very wide pH range, J. Melder, S. Mebs, P. A. Heizmann, R. Lang, H. Dau, P. Kurz, Journal of Materials Chemistry A 2019, 7, 25333–25346, 10.1039/c9ta08804k
Geometry of the Catalytic Active Site in [FeFe]-Hydrogenase Is Determined by Hydrogen Bonding and Proton Transfer, J. Duan, S. Mebs, K. Laun, F. Wittkamp, J. Heberle, T. Happe, E. Hofmann, U. P. Apfel, M. Winkler, M. Senger, M. Haumann, S. T. Stripp, ACS Catalysis 2019, 9, 9140–9149, 10.1021/acscatal.9b02203
Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O -Tolerant [NiFe] Hydrogenase, A. C. Schulz, S. Frielingsdorf, P. Pommerening, L. Lauterbach, G. Bistoni, F. Neese, M. Oestreich, O. Lenz, Journal of the American Chemical Society 2019, 142, 1457–1464, 10.1021/jacs.9b11506
Revealing the Mechanism of Multiwalled Carbon Nanotube Growth on Supported Nickel Nanoparticles by in Situ Synchrotron X-ray Diffraction, Density Functional Theory, and Molecular Dynamics Simulations, A. Gili, L. Schlicker, M. F. Bekheet, O. Görke, D. Kober, U. Simon, P. Littlewood, R. Schomäcker, A. Doran, D. Gaissmaier, T. Jacob, S. Selve, A. Gurlo, ACS Catalysis 2019, 9, 6999–7011, 10.1021/acscatal.9b00733
A Spectroscopic and Computationally Minimal Approach to the Analysis of Charge‐Transfer Processes in Conformationally Fluxional Mixed‐Valence and Heterobimetallic Complexes, S. Gückel, J. B. G. Gluyas, S. G. Eaves, P. Safari, D. S. Yufit, A. N. Sobolev, M. Kaupp, P. J. Low, Chemistry – A European Journal 2019, 10.1002/chem.201901200
Host–Guest Chemistry Meets Electrocatalysis: Cucurbit[6]uril on a Au Surface as a Hybrid System in CO Reduction, A. Wagner, K. H. Ly, N. Heidary, I. Szabó, T. Földes, K. I. Assaf, S. J. Barrow, K. Sokołowski, M. Al-Hada, N. Kornienko, M. F. Kuehnel, E. Rosta, I. Zebger, W. M. Nau, O. A. Scherman, E. Reisner, ACS Catalysis 2019, 10, 751–761, 10.1021/acscatal.9b04221
Probing Structure and Reaction Dynamics of Proteins Using Time-Resolved Resonance Raman Spectroscopy, D. Buhrke, P. Hildebrandt, Chemical Reviews 2019, 120, 3577–3630, 10.1021/acs.chemrev.9b00429
Spectroscopic, thermodynamic and computational evidence of the locations of the FADs in the nitrogen fixation-associated electron transfer flavoprotein, N. Mohamed-Raseek, H. D. Duan, P. Hildebrandt, M. A. Mroginski, A. F. Miller, Chemical Science 2019, 10, 7762–7772, 10.1039/c9sc00942f
MerMAIDs: a family of metagenomically discovered marine anion-conducting and intensely desensitizing channelrhodopsins, J. Oppermann, P. Fischer, A. Silapetere, B. Liepe, S. Rodriguez-Rozada, J. Flores-Uribe, E. Peter, A. Keidel, J. Vierock, J. Kaufmann, M. Broser, M. Luck, F. Bartl, P. Hildebrandt, J. S. Wiegert, O. Béjà, P. Hegemann, J. Wietek, Nature Communications 2019, 10, 10.1038/s41467-019-11322-6
Engineered Passive Potassium Conductance in the KR2 Sodium Pump, A. Vogt, A. Silapetere, C. Grimm, F. Heiser, M. Ancina Möller, P. Hegemann, Biophysical Journal 2019, 116, 1941–1951, 10.1016/j.bpj.2019.04.001
Tracking Pore Hydration in Channelrhodopsin by Site-Directed Infrared-Active Azido Probes, B. S. Krause, J. C. D. Kaufmann, J. Kuhne, J. Vierock, T. Huber, T. P. Sakmar, K. Gerwert, F. J. Bartl, P. Hegemann, Biochemistry 2019, 58, 1275–1286, 10.1021/acs.biochem.8b01211
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Absorption and Emission Spectroscopic Investigation of the Thermal Dynamics of the Archaerhodopsin 3 Based Fluorescent Voltage Sensor QuasAr1, Penzkofer, Silapetere, Hegemann, International Journal of Molecular Sciences 2019, 20, 4086–0, 10.3390/ijms20174086
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Proton Transfer Pathways between Active Sites and Proximal Clusters in the Membrane-Bound [NiFe] Hydrogenase, D. Tombolelli, M. A. Mroginski, The Journal of Physical Chemistry B 2019, 123, 3409–3420, 10.1021/acs.jpcb.9b00617
Vibrationally Broadened Optical Spectra of Selected Radicals and Cations Derived from Adamantane: A Time-Dependent Correlation Function Approach, T. Xiong, P. Saalfrank, The Journal of Physical Chemistry A 2019, 123, 8871–8880, 10.1021/acs.jpca.9b03305
Stereochemical Elucidation of Natural Products from Residual Chemical Shift Anisotropies in a Liquid Crystalline Phase, X. L. Li, L. P. Chi, A. Navarro-Vázquez, S. Hwang, P. Schmieder, X. M. Li, X. Li, S. Q. Yang, X. Lei, B. G. Wang, H. Sun, Journal of the American Chemical Society 2019, 142, 2301–2309, 10.1021/jacs.9b10961
In Situ Structural Restraints from Cross-Linking Mass Spectrometry in Human Mitochondria, P. S. J. Ryl, M. Bohlke-Schneider, S. Lenz, L. Fischer, L. Budzinski, M. Stuiver, M. M. L. Mendes, L. Sinn, F. J. O’Reilly, J. Rappsilber, Journal of Proteome Research 2019, 19, 327–336, 10.1021/acs.jproteome.9b00541
A Cobalt‐Based Amorphous Bifunctional Electrocatalysts for Water‐Splitting Evolved from a Single‐Source Lazulite Cobalt Phosphate, P. W. Menezes, C. Panda, C. Walter, M. Schwarze, M. Driess, Advanced Functional Materials 2019, 29, 1808632–0, 10.1002/adfm.201808632
Boosting Water Oxidation through In Situ Electroconversion of Manganese Gallide: An Intermetallic Precursor Approach, P. W. Menezes, C. Walter, J. N. Hausmann, R. Beltrán‐Suito, C. Schlesiger, S. Praetz, V. Yu. Verchenko, A. V. Shevelkov, M. Driess, Angewandte Chemie International Edition 2019, 58, 16569–16574, 10.1002/anie.201909904
Boosting Electrocatalytic Hydrogen Evolution Activity with a NiPt @NiS Heteronanostructure Evolved from a Molecular Nickel–Platinum Precursor, C. Panda, P. W. Menezes, S. Yao, J. Schmidt, C. Walter, J. N. Hausmann, M. Driess, Journal of the American Chemical Society 2019, 141, 13306–13310, 10.1021/jacs.9b06530
Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules, Y. Wang, M. Karni, S. Yao, A. Kaushansky, Y. Apeloig, M. Driess, Journal of the American Chemical Society 2019, 141, 12916–12927, 10.1021/jacs.9b06603
Amorphous outperforms crystalline nanomaterials: surface modifications of molecularly derived CoP electro(pre)catalysts for efficient water-splitting, R. Beltrán-Suito, P. W. Menezes, M. Driess, Journal of Materials Chemistry A 2019, 7, 15749–15756, 10.1039/C9TA04583J
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From a Molecular Single-Source Precursor to a Selective High-Performance RhMnO Catalyst for the Conversion of Syngas to Ethanol, P. Preikschas, J. Bauer, X. Huang, S. Yao, R. Naumann d'Alnoncourt, R. Kraehnert, A. Trunschke, F. Rosowski, M. Driess, ChemCatChem 2019, 11, 885–892, 10.1002/cctc.201801978
Isolable Silylene Ligands Can Boost Efficiencies and Selectivities in Metal‐Mediated Catalysis, Y. Zhou, M. Driess, Angewandte Chemie International Edition 2019, 58, 3715–3728, 10.1002/anie.201811088
Discriminating changes in intracellular NADH/NAD+ levels due to anoxicity and H2 supply in R. eutropha cells using the Frex fluorescence sensor, S. Wilkening, F. J. Schmitt, O. Lenz, I. Zebger, M. Horch, T. Friedrich, Biochimica et Biophysica Acta (BBA) - Bioenergetics 2019, 1860, 148062–0, 10.1016/j.bbabio.2019.148062
The Pathogenic TSH β-subunit Variant C105Vfs114X Causes a Modified Signaling Profile at TSHR, L. Kalveram, G. Kleinau, K. Szymańska, P. Scheerer, A. Rivero-Müller, A. Grüters-Kieslich, H. Biebermann, International Journal of Molecular Sciences 2019, 20, 5564–0, 10.3390/ijms20225564
Recurrent convergent evolution at amino acid residue 261 in fish rhodopsin, J. Hill, E. D. Enbody, M. E. Pettersson, C. G. Sprehn, D. Bekkevold, A. Folkvord, L. Laikre, G. Kleinau, P. Scheerer, L. Andersson, Proceedings of the National Academy of Sciences 2019, 116, 18473–18478, 10.1073/pnas.1908332116
Signal Transduction and Pathogenic Modifications at the Melanocortin-4 Receptor: A Structural Perspective, N. Heyder, G. Kleinau, M. Szczepek, D. Kwiatkowski, D. Speck, L. Soletto, J. M. Cerdá-Reverter, H. Krude, P. Kühnen, H. Biebermann, P. Scheerer, Frontiers in Endocrinology 2019, 10, 1–18, 10.3389/fendo.2019.00515
The Axonal Membrane Protein PRG2 Inhibits PTEN and Directs Growth to Branches, A. Brosig, J. Fuchs, F. Ipek, C. Kroon, S. Schrötter, M. Vadhvani, A. Polyzou, J. Ledderose, M. van Diepen, H. G. Holzhütter, T. Trimbuch, N. Gimber, J. Schmoranzer, I. Lieberam, C. Rosenmund, C. Spahn, P. Scheerer, M. Szczepek, G. Leondaritis, B. J. Eickholt, Cell Reports 2019, 29, 2028–2040, 10.1016/j.celrep.2019.10.039
Evaluation of a rare glucose‐dependent insulinotropic polypeptide receptor variant in a patient with diabetes, S. F. Jacobi, N. Khajavi, G. Kleinau, A. Teumer, P. Scheerer, G. Homuth, H. Völzke, S. Wiegand, P. Kühnen, H. Krude, M. Gong, K. Raile, H. Biebermann, Diabetes, Obesity and Metabolism 2019, 21, 1168–1176, 10.1111/dom.13634
A UV/Vis Spectroscopy-Based Assay for Monitoring of Transformations Between Nucleosides and Nucleobases, F. Kaspar, R. T. Giessmann, N. Krausch, P. Neubauer, A. Wagner, M. Gimpel, Methods and Protocols 2019, 2, 60–0, 10.3390/mps2030060
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Molecular Engineering of Conjugated Acetylenic Polymers for Efficient Cocatalyst‐free Photoelectrochemical Water Reduction, H. Sun, I. H. Öner, T. Wang, T. Zhang, O. Selyshchev, C. Neumann, Y. Fu, Z. Liao, S. Xu, Y. Hou, A. Turchanin, D. R. T. Zahn, E. Zschech, I. M. Weidinger, J. Zhang, X. Feng, Angewandte Chemie International Edition 2019, 58, 10368–10374, 10.1002/anie.201904978
Efficient Light-Induced p Modulation Coupled to Base-Catalyzed Photochromism, J. Gurke, Š. Budzák, B. M. Schmidt, D. Jacquemin, S. Hecht, Angewandte Chemie International Edition 2018, 57, 4797–4801, 10.1002/anie.201801270
Two-Dimensional Nonlinear Optical Switching Materials: Molecular Engineering toward High Nonlinear Optical Contrasts, M. Hänsel, C. Barta, C. Rietze, M. Utecht, K. Rück-Braun, P. Saalfrank, P. Tegeder, The Journal of Physical Chemistry C 2018, 122, 25555–25564, 10.1021/acs.jpcc.8b08212
Plasmonic Cu/CuCl/Cu2S/Ag and Cu/CuCl/Cu2S/Au Supports with Peroxidase-Like Activity: Insights from Surface Enhanced Raman Spectroscopy, W. Song, P. Hildebrandt, I. M. Weidinger, Zeitschrift für Physikalische Chemie 2018, 232, 1541–1550, 10.1515/zpch-2018-1126
Catalytic Generation and Chemoselective Transfer of Nucleophilic Hydrides from Dihydrogen, F. Pape, L. T. Brechmann, J. F. Teichert, Chemistry – A European Journal 2018, 10.1002/chem.201805530
Effiziente lichtinduzierte p -Modulation, gekoppelt mit basenkatalysierter Photochromie, J. Gurke, Š. Budzák, B. M. Schmidt, D. Jacquemin, S. Hecht, Angewandte Chemie 2018, 130, 4888–4893, 10.1002/ange.201801270
Oxidative and reductive cyclization in stiff dithienylethenes, M. Kleinwächter, E. Teichmann, L. Grubert, M. Herder, S. Hecht, Beilstein Journal of Organic Chemistry 2018, 14, 2812–2821, 10.3762/bjoc.14.259
Selective Oxidation of -Butane over Vanadium Phosphate Based Catalysts: Reaction Network and Kinetic Analysis, C. Schulz, F. Pohl, M. Driess, R. Glaum, F. Rosowski, B. Frank, Industrial & Engineering Chemistry Research 2018, 58, 2492–2502, 10.1021/acs.iecr.8b04328
Silicon-Mediated Selective Homo- and Heterocoupling of Carbon Monoxide, Y. Wang, A. Kostenko, T. J. Hadlington, M. P. Luecke, S. Yao, M. Driess, Journal of the American Chemical Society 2018, 141, 626–634, 10.1021/jacs.8b11899
An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity, Y. Wang, M. Karni, S. Yao, Y. Apeloig, M. Driess, Journal of the American Chemical Society 2018, 141, 1655–1664, 10.1021/jacs.8b11605
A New Domain of Reactivity for High-Valent Dinuclear [M(μ-O) M′] Complexes in Oxidation Reactions, X. Engelmann, S. Yao, E. R. Farquhar, T. Szilvási, U. Kuhlmann, P. Hildebrandt, M. Driess, K. Ray, Angewandte Chemie 2017, 129, 303–307, 10.1002/ange.201607611