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Cationic Bis(hydrosilane)—Coinage‐Metal Complexes: Synthesis, Characterization, and Use as Catalysts for Outer‐Sphere C=O Hydrosilylation Not Involving Metal Hydrides,
H. Gao, S. Kwon, H. Kwon, E. Irran, H. F. T. Klare, M. Baik, M. Oestreich,
Angewandte Chemie International Edition
2024,
39,
202409582–0,
10.1002/anie.202409582
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Silylium-Ion-Initiated Twofold Halodealkylation of Fully Alkylated Silanes,
T. Randt, T. He, H. F. T. Klare, M. Oestreich,
Synthesis
2024,
56,
3054–3062,
10.1055/a-2350-1323
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Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions,
P. W. Long, T. He, H. F. T. Klare, M. Oestreich,
Synlett
2024,
35,
941–951,
10.1055/a-2188-1842
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Catalytically Generated Meerwein’s Salt-Type Oxonium Ions for Friedel–Crafts C(sp2)–H Methylation with Methanol,
T. He, H. F. T. Klare, M. Oestreich,
Journal of the American Chemical Society
2023,
145,
3795–3801,
10.1021/jacs.2c13341
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Silylium Ion Initiated Intramolecular Friedel–Crafts-Type Cyclization of 1,1-Difluoroalkenes with Subsequent Hydrodefluorination of C(sp3)–F Bonds,
A. Roy, H. Gao, H. F. T. Klare, M. Oestreich,
Synthesis
2023,
55,
1602–1612,
10.1055/a-2009-8114
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Arenium-ion-catalysed halodealkylation of fully alkylated silanes,
T. He, H. F. T. Klare, M. Oestreich,
Nature
2023,
623,
538–543,
10.1038/s41586-023-06646-9
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Intermolecular Carbosilylation of α‐Olefins with C(sp )−C(sp) Bond Formation Involving Silylium‐Ion Regeneration,
T. He, Z. Qu, H. F. T. Klare, S. Grimme, M. Oestreich,
Angewandte Chemie International Edition
2022,
61,
202203347–202203347,
10.1002/anie.202203347
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Perdeuteration of Deactivated Aryl Halides by H/D Exchange under Superelectrophile Catalysis,
T. He, H. F. T. Klare, M. Oestreich,
Journal of the American Chemical Society
2022,
144,
4734–4738,
10.1021/jacs.2c00080
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Competition for Hydride Between Silicon and Boron: Synthesis and Characterization of a Hydroborane‐Stabilized Silylium Ion,
H. Gao, R. Müller, E. Irran, H. F. T. Klare, M. Kaupp, M. Oestreich,
Chemistry – A European Journal
2022,
28,
202104464–202104464,
10.1002/chem.202104464
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Silylium-Ion Regeneration by Protodesilylation Enables Friedel–Crafts Alkylation with Less Isomerization and No Defunctionalization,
T. He, H. F. T. Klare, M. Oestreich,
ACS Catalysis
2021,
11,
12186–12193,
10.1021/acscatal.1c03602
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The Power of the Proton: From Superacidic Media to Superelectrophile Catalysis,
H. F. T. Klare, M. Oestreich,
Journal of the American Chemical Society
2021,
143,
15490–15507,
10.1021/jacs.1c07614
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Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts,
H. F. T. Klare, L. Albers, L. Süsse, S. Keess, T. Müller, M. Oestreich,
Chemical Reviews
2021,
121,
5889–5985,
10.1021/acs.chemrev.0c00855
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Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes,
T. He, G. Wang, P. W. Long, S. Kemper, E. Irran, H. F. T. Klare, M. Oestreich,
Chemical Science
2021,
12,
569–575,
10.1039/D0SC05553K
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B(C F ) -Catalyzed Hydrosilylation of Vinylcyclopropanes,
P. W. Long, T. He, M. Oestreich,
Organic Letters
2020,
22,
7383–7386,
10.1021/acs.orglett.0c02751
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Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration,
T. He, G. Wang, V. Bonetti, H. F. T. Klare, M. Oestreich,
Angewandte Chemie International Edition
2020,
59,
12186–12191,
10.1002/anie.202004320
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Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion,
Q. Wu, A. Roy, G. Wang, E. Irran, H. F. T. Klare, M. Oestreich,
Angewandte Chemie International Edition
2020,
59,
10523–10526,
10.1002/anie.202003799
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General Synthesis and Optical Properties of -Aryl- ′-Silyldiazenes,
C. Chauvier, L. Finck, S. Hecht, M. Oestreich,
Organometallics
2019,
38,
4679–4686,
10.1021/acs.organomet.9b00654
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Formyltetrahydrofolate Decarbonylase Synthesizes the Active Site CO Ligand of O -Tolerant [NiFe] Hydrogenase,
A. C. Schulz, S. Frielingsdorf, P. Pommerening, L. Lauterbach, G. Bistoni, F. Neese, M. Oestreich, O. Lenz,
Journal of the American Chemical Society
2019,
142,
1457–1464,
10.1021/jacs.9b11506
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Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions,
Q. Wu, A. Roy, E. Irran, Z. Qu, S. Grimme, H. F. T. Klare, M. Oestreich,
Angewandte Chemie International Edition
2019,
58,
17307–17311,
10.1002/anie.201911282
