UniSysCat Publications

  • Expanding the scope of resonance Raman spectroscopy in hydrogenase research: New observable states and reporter vibrations, C. C. M. Bernitzky, G. Caserta, S. Frielingsdorf, J. Schoknecht, A. Schmidt, P. Scheerer, O. Lenz, P. Hildebrandt, C. Lorent, I. Zebger, M. Horch, Journal of Inorganic Biochemistry 2025, 262, 112741–0, 10.1016/j.jinorgbio.2024.112741
  • Light‐Induced Electron Transfer in a [NiFe] Hydrogenase Opens a Photochemical Shortcut for Catalytic Dihydrogen Cleavage, C. Karafoulidi‐Retsou, C. Lorent, S. Katz, Y. Rippers, H. Matsuura, Y. Higuchi, I. Zebger, M. Horch, Angewandte Chemie International Edition 2024, 10.1002/anie.202409065
  • Lichtinduzierter Elektronentransfer in einer [NiFe]‐Hydrogenase: Eine Photochemische Abkürzung für die Katalytische Wasserstoffspaltung, C. Karafoulidi‐Retsou, C. Lorent, S. Katz, Y. Rippers, H. Matsuura, Y. Higuchi, I. Zebger, M. Horch, Angewandte Chemie 2024, 136, 10.1002/ange.202409065
  • Reversible Glutamate Coordination to High-Valent Nickel Protects the Active Site of a [NiFe] Hydrogenase from Oxygen, C. J. Kulka-Peschke, A. C. Schulz, C. Lorent, Y. Rippers, S. Wahlefeld, J. Preissler, C. Schulz, C. Wiemann, C. C. M. Bernitzky, C. Karafoulidi-Retsou, S. L. D. Wrathall, B. Procacci, H. Matsuura, G. M. Greetham, C. Teutloff, L. Lauterbach, Y. Higuchi, M. Ishii, N. T. Hunt, O. Lenz, I. Zebger, M. Horch, Journal of the American Chemical Society 2022, 144, 17022–17032, 10.1021/jacs.2c06400
  • Understanding 2D-IR Spectra of Hydrogenases: A Descriptive and Predictive Computational Study, Y. Rippers, B. Procacci, N. T. Hunt, M. Horch, Catalysts 2022, 12, 988–0, 10.3390/catal12090988
  • Ultrafast 2D-IR spectroscopy of [NiFe] hydrogenase from reveals the role of the protein scaffold in controlling the active site environment, S. L. D. Wrathall, B. Procacci, M. Horch, E. Saxton, C. Furlan, J. Walton, Y. Rippers, J. N. Blaza, G. M. Greetham, M. Towrie, A. W. Parker, J. Lynam, A. Parkin, N. T. Hunt, Physical Chemistry Chemical Physics 2022, 24, 24767–24783, 10.1039/d2cp04188j
  • Exploring Structure and Function of Redox Intermediates in [NiFe]‐Hydrogenases by an Advanced Experimental Approach for Solvated, Lyophilized and Crystallized Metalloenzymes, C. Lorent, V. Pelmenschikov, S. Frielingsdorf, J. Schoknecht, G. Caserta, Y. Yoda, H. Wang, K. Tamasaku, O. Lenz, S. P. Cramer, M. Horch, L. Lauterbach, I. Zebger, Angewandte Chemie International Edition 2021, 60, 15854–15862, 10.1002/anie.202100451
  • Ein neuer Aufbau zur Untersuchung der Struktur und Funktion von solvatisierten, lyophilisierten und kristallinen Metalloenzymen – veranschaulicht anhand von [NiFe]‐Hydrogenasen, C. Lorent, V. Pelmenschikov, S. Frielingsdorf, J. Schoknecht, G. Caserta, Y. Yoda, H. Wang, K. Tamasaku, O. Lenz, S. P. Cramer, M. Horch, L. Lauterbach, I. Zebger, Angewandte Chemie 2021, 133, 15988–15996, 10.1002/ange.202100451
  • Shedding Light on Proton and Electron Dynamics in [FeFe] Hydrogenases, C. Lorent, S. Katz, J. Duan, C. J. Kulka, G. Caserta, C. Teutloff, S. Yadav, U. P. Apfel, M. Winkler, T. Happe, M. Horch, I. Zebger, Journal of the American Chemical Society 2020, 142, 5493–5497, 10.1021/jacs.9b13075
  • Hydrogen Development, U. P. Apfel, W. Weigand, M. Horch, I. Zebger, O. Lenz, T. Fujishiro in Bioorganometallic Chemistry (Hrsg.: Wolfgang Weigand, Ulf-Peter Apfel), De Gruyter, 2020, 13–136, ISBN: 9783110496505
  • Understanding the structure and dynamics of hydrogenases by ultrafast and two-dimensional infrared spectroscopy, M. Horch, J. Schoknecht, S. L. D. Wrathall, G. M. Greetham, O. Lenz, N. T. Hunt, Chemical Science 2019, 10, 8981–8989, 10.1039/C9SC02851J
  • X‐ray Crystallography and Vibrational Spectroscopy Reveal the Key Determinants of Biocatalytic Dihydrogen Cycling by [NiFe] Hydrogenases, Y. Ilina, C. Lorent, S. Katz, J. Jeoung, S. Shima, M. Horch, I. Zebger, H. Dobbek, Angewandte Chemie International Edition 2019, 58, 18710–18714, 10.1002/anie.201908258
  • Discriminating changes in intracellular NADH/NAD+ levels due to anoxicity and H2 supply in R. eutropha cells using the Frex fluorescence sensor, S. Wilkening, F. J. Schmitt, O. Lenz, I. Zebger, M. Horch, T. Friedrich, Biochimica et Biophysica Acta (BBA) - Bioenergetics 2019, 1860, 148062–0, 10.1016/j.bbabio.2019.148062